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US 4,213,892 AGranted
Process for preparing oxidatively-stable polymers by reaction with antioxidant in the presence of free radical
OwnerGerald Scottinventor
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Abstract
Polymers are rendered more oxidatively stable by reaction with an antioxidant or stabilizer, generally a vinyl-group- or thiol group-containing antioxidant, in the presence of a free radical which may be produced by a redox system or ultra-violet light. The resulting polymers can be used as such or can be used as additives in other polymers to stabilize the latter.
Claims11
A process for preparing an oxidatively stable polymer which comprises reacting the polymer with an antioxidant of the formula:
- ##STR16## in which R.sub.1 and R.sub.2 each independently represents a hydrogen atom or a tertiary alkyl radical such that at least one represents a tertiary alkyl radical and R.sub.3 represents a hydrogen atom or an alkyl, hydroxy, hydroxyalkyl, alkoxyalkyl or mercaptoalkyl radical, said R radicals optionally being substituted by aromatic phenolic or aromatic amine groups, in the presence of a free radical with the proviso that when the free radical is produced by a free radical generator, said generator produces free radicals at a temperature below about 120.degree. C.
Dependencies are inferred from the claim text.