N,N-'-Dihydroxyalkyl ester substituted imidazolidinediones and coating compositions containing same
AssigneePPG Industries, Inc.
InventorsRostyslaw Dowbenko, Ronald J. Lewarchik, William J. Birkmeyer
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Abstract
Resin mixtures of N,N'-dihydroxyalkyl ester substituted imidazolidinediones are especially useful in coating compositions having a low organic solvent content. The substituted imidazolidinediones have the formula ##STR1## wherein R and R' are independently hydrogen or hydrocarbon groups having from 1 to 8 carbon atoms, X is ##STR2## where the R" groups are independently hydrocarbon groups having from 1 to 17 carbon atoms.
Claims33
A resin mixture of N,N'-dihydroxyalkyl ester substituted imidazolidinediones having the formula:
- ##STR9## wherein R and R' are independently hydrogen or hydrocarbon groups having from 1 to 8 carbon atoms, X is ##STR10## where the R" groups are independently hydrocarbon groups having from 1 to 17 carbon atoms.
A process for making a resin mixture of N,N'-dihydroxyalkyl ester substituted imidazolidinediones comprising the step of reacting (1) an imidazolidinedione of the formula:
- ##STR11## wherein R and R' are independently hydrogen or hydrocarbon groups having from 1 to 8 carbon atoms;
- with (2) a glycidyl ester of the formula:
- ##STR12## wherein R" is a hydrocarbon group having from 1 to 17 carbon atoms at a temperature of from about 50.degree. C. to about 200.degree. C. in the presence of a catalyst so as to obtain a mixture of compounds having the formula:
- ##STR13## where X is ##STR14## with R, R' and R" being as defined above.
A coating composition containing less than about 40 percent organic solvent, consisting essentially of:
- (a) from about 5 percent to about 90 percent of a resin mixture of N,N'-dihydroxyalkyl ester substituted imidazolidinediones having the formula:
- ##STR15## wherein R and R' are independently hydrogen or hydrocarbon groups having from 1 to 8 carbon atoms, X is ##STR16## where the R" groups are independently hydrocarbon groups having from 1 to 17 carbon atoms;
- and
- (b) from about 5 percent to about 80 percent of a crosslinking agent selected from the group consisting of aminoplasts, isocyanates, blocked isocyanates, phenoplasts and mixtures thereof.
Dependencies are inferred from the claim text.