Aqueous fortified rosin dispersions
AssigneeHercules Incorporated
InventorsRichrd M. Hughes, Heinz Warnecke
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Abstract
In the inversion process for preparing paper size from fortified rosin wherein a water-soluble dispersing agent including an ethylene oxide sulphate group is used to provide a stable aqueous dispersion of fortified rosin; and an invert size produced by such a process.
Claims41
In the inversion process of preparing paper size from fortified rosin wherein molten fortified rosin and water containing a dispersing agent are first mixed to provide a water-in-oil emulsion wherein the molten fortified resin is the continuous phase and the water is the disperse phase and the emulsion is subsequently inverted by the addition of water to provide an emulsion wherein the water is the continuous phase and the fortified rosin is the disperse phase, the improvement wherein there is employed as the dispersing agent one or more water-soluble compounds of the formulae ##STR8## wherein in formula (I), R is a normal or branched chain alkyl containing from 4 through 18 carbon atoms;
- wherein in formula (II) R' is a normal or branched chain alkyl or alkenyl or fused ring cycloalkyl containing from 10 through 20 carbon atoms;
- wherein in formulas (I) and (II), n is an integer such that of the molecular weight of each anion, from about 27% to about 75% thereof is attributable to the (CH.sub.2 CH.sub.2 O) group, and M.sup.+ is a monovalent cation, other than hydrogen, that will allow substantial dissolution of said dispersing agent in water and will remain in solution during the preparation of the water-in-oil emulsion.
An invert size for use in sizing paper comprising an aqueous dispersion of fortified rosin stabilized by a dispersing agent, said dispersing agent being one or more water-soluble compounds of the formulas ##STR9## wherein in formula (I), R is a normal or branched chain alkyl containing from 4 through 18 carbon atoms;
- wherein in formula (II) R' is a normal or branched chain alkyl or alkenyl or fused ring cycloalkyl containing from 10 through 20 carbon atoms;
- wherein in formulas (I) and (II), n is an integer such that of the molecular weight of each anion, from about 27% to about 75% thereof is attributable to the (CH.sub.2 CH.sub.2 O) group, and M.sup.+ is a monovalent cation, other than hydrogen.
Dependencies are inferred from the claim text.