US 4,199,327 AGranted

Process for gasification of coal to maximize coal utilization and minimize quantity and ecological impact of waste products

AssigneeKaiser Engineers, Inc.

InventorsHugh G. Hempill, Robert E. Hurney

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Abstract

Coarse, graded coal is fed to a pressurized relatively fixed bed, non-slagging gasifier from which crude gas is recovered. Fine coal is slurried in an aqueous mixture comprising the discharge from the relatively fixed bed gasifier, which discharge is composed of hydrocarbons, phenolic water and other liquids as major components and additional makeup water, if required, and the slurry is fed to a slagging, pressurized entrained flow gasifier from which additional crude gas is recovered. The two streams of gas are cleaned and then used to meet a variety of demands, including, but not limited to, gas turbine generation of electric power, manufacture of synthetic natural gas and manufacture of methanol.

Claims13

Dependent claims

A process for the gasification of coal wherein the total available coal is utilized in separate gasification systems and is converted into environmentally acceptable gaseous fuel and the quantity and type of waste products from said gasifier systems are kept to a minimum, comprising the following steps:

(a) separating coal into a coarse fraction and a fine fraction,
(b) feeding the coarse fraction to a fixed bed non-slagging gasifier in which,
(i) oxygen containing gas and steam are blown through said fixed bed of coal within said pressurized gasifier at temperatures to cause the coal to gasify and break down into crude gas containing hydrocarbons and other gaseous and particulate impurities,
(ii) passing said gas through scrubbers and through condensers to remove particulates and condensable components from said impurities as a liquid stream and to a first gas purification system for removal of hydrogen sulfide and coabsorbed carbon dioxide,
(c) forming a mixture of said liquid stream and said fine fraction of coal to form a pumpable slurry, said liquid stream containing particulates and condensable impurities removed from the crude gas stream from said fixed-bed gasifier and comprising tars, oils and phenol water in an amount to contribute significant fuel value to said slurry,
(d) passing said slurry with oxygen containing gas to an entrained flow gasifier maintained under pressure,
(i) rapidly reacting said mixture in said entrained flow gasifier to form a crude gas,
(ii) passing said gas from said entrained flow gasifier through particulate removal scrubbers and then to heat exchangers to a second gas purification system to remove hydrogen sulfide and coabsorbed carbon dioxide and
(iii) removing the ash from said entrained flow gasifier, and
(e) recovering said streams of purified gas.

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(a) separating coal into a coarse fraction of not less than 1/8 in. particle size and a fine fraction wherein at least 70% of particles pass a 200 mesh screen,
(b) feeding the coarse fraction to a fixed bed non-slagging gasifier in which,
(i) air and steam are blown through said fixed bed of coal with said gasifier at a pressure of about 350 lbs/sq. in. and at a temperature of about 900.degree. F. to cause the coal to gasify and break down into crude gas of about 150 BTU containing hydrocarbons and other gaseous and particulate impurities.
(ii) passing said 150 BTU gas at an entrance temperature of about 900.degree. F. through scrubbers and through condensers to remove particulates and condensable components from said impurities as a liquid stream at a temperature of about 100.degree. F. and passing said 150 BTU crude gas stream into a purification system for removal of hydrogen sulfide and coabsorbed carbon dioxide,
(c) mixing said liquid stream with said fine fraction of coal and any required additional water to form a pumpable slurry, said liquid stream comprising tars, oils and phenol water in an amount to contribute significant fuel valve to said slurry,
(d) passing said slurry with oxygen to an entrained flow gasifier maintained under a pressure of about 500 lbs./sq. in.,
(i) rapidly reacting said mixture in said entrained flow gasifier to form a crude gas of about 350 BTU at a temperature of about 2,000.degree. F.,
(ii) passing said stream of 350 BTU crude gas through particulate removal scrubbers and heat exchangers to a gas purification system to remove hydrogen sulfide and coabsorbed carbon dioxide, and
(iii) removing the ash from the gasifier and quenching it to temperatures for disposal.
(e) recovering said separate streams of purified gas.

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Dependencies are inferred from the claim text.