Hot melt adhesive comprising fluorocarbon elastomer, ethylene copolymer and tackifier
AssigneeRaychem Corporation
InventorsYuan Chao, George Pieslak
Life of this patent
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Abstract
Novel hot melt adhesives comprise a fluoroelastomer, an ethylene copolymer and a tackifier. Preferably the adhesive contains 20 to 40% by weight of the fluorocarbon elastomer, 40 to 60% by weight of the ethylene copolymer and 10 to 30% by weight of the tackifier. The adhesives will bond well to a wide variety of substrates, including substrates of low surface energy such as partially fluorinated polymers, even after prolonged exposure to high temperatures.
Claims14
A hot melt adhesive which comprises
- (1) 10 to 90% by weight of a crystalline ethylene copolymer comprising at least 50 mole % of units derived from ethylene and at least 5 mole % of units derived from at least one unsaturated comonomer containing at least one polar group;
- (2) 5 to 60% by weight of a fluorocarbon elastomer consisting of one or more fluorinated monomers containing ethylenic unsaturation and from 0 to 30 mole % other ethylenically unsaturated monomers;
- and
- (3) 5 to 40% by weight of a tackifier, all percentages by weight being based on the total weight of the three compounds.
A hot melt adhesive which has a softening point of 60.degree. to 100.degree. C. and which comprises
- (1) 10 to 90% by weight of a crystalline ethylene copolymer comprising at least 60 mole % of units derived from ethylene and 10 to 40 mole % of units derived from at least one unsaturated comonomer containing at least one polar group;
- (2) 5 to 60% by weight of a fluorocarbon elastomer comprising 30 to 70 mole % of units derived from vinylidene fluoride and 70 to 30 mole % of units derived from a comonomer selected from hexafluoropropylene, tetrafluoroethylene and chlorotrifluorethylene;
- and
- (3) 5 to 40% by weight of a tackifier which is a polymer of at least one compound of the formula
- R.sub.1 CH=CR.sub.2 R.sub.3
- wherein R.sub.1, R.sub.2 and R.sub.3 are independently selected from substituted and unsubstituted alkyl, alkenyl, aryl, aralkyl and alkaryl radicals containing 1 to 10 carbon atoms, all percentages by weight being based on the total weight of the three components.
A composition comprising:
- (1) 10 to 90% by weight of an ethylene copolymer comprising units derived from ethylene and units derived from at least one comonomer containing polar groups selected from the group consisting of carboxy groups, carboxylic ester groups, alkyl carbonyloxy groups, cyano groups, hydroxy groups, and combinations thereof;
- (2) 5 to 60% by weight of a fluorocarbon elastomer comprising units derived from vinylidene fluoride and at least one other fluorinated monomer;
- and
- (3) 5 to 40% by weight of a tackifier, all percentages by weight being based on the total weight of the three components.
A composition comprising:
- (1) 10 to 90% by weight of a crystalline ethylene copolymer comprising at least 50 mole % of units derived from ethylene and at least 5 mole % of units derived from at least one unsaturated comonomer containing at least one polar group;
- (2) 5 to 60% by weight of a fluorocarbon elastomer comprising units derived from vinylidene fluoride and at least one other fluorinated monomer;
- and
- (3) 5 to 40% by weight of a tackifier, all percentages by weight being based on the total weight of the three components.
Dependencies are inferred from the claim text.