Oxidation of waxes in the presence of long chain quaternary ammonium and phosphonium compounds
AssigneeAshland Oil, Inc.
InventorDonald D. Carlos
Life of this patent
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Abstract
The oxidation of hydrocarbon waxes to corresponding fatty acids through the use of conventional catalysts and oxidizing gases such as air is promoted by the addition of quaternary ammonium and phosphonium salts to the catalyst-wax mixture.
Claims7
A process for oxidizing a liquid mixture of saturated paraffinic hydrocarbons having an average of about 20 to about 100 carbon atoms per molecule to a desired acid number comprising blowing an oxidizing gas through said liquid mixture in the presence of an oxidizing catalyst and a promoting amount of a quaternary salt having the formula:
- ##STR3## where R.sub.1 is an aliphatic hydrocarbon radical of 12 or more carbon atoms, R.sub.2 is an aliphatic hydrocarbon radical of 1-12 carbon atoms, A is nitrogen or phosphorus and X.sup..sym. is chloride, bromide, iodide, sulfate or bisulfate.
A process for oxidizing liquid hydrocarbon fractions to a desired acid number comprising blowing an oxidizing gas through said liquid hydrocarbon in the presence of an oxidizing catalyst and a promoting amount of dodecyltrimethylammonium chloride.
A process for oxidizing liquid hydrocarbon fractions to a desired acid number comprising blowing an oxidizing gas through said liquid hydrocarbon in the presence of an oxidizing catalyst and a promoting amount of a mixture of quaternary ammonium compounds having the formula:
- ##STR4## wherein R collectively represents the alkyl residue of a primary alcohol mixture composed of 30-70 wt. percent of (a) straight-chain C.sub.16 -C.sub.22 alcohols and correspondingly from 70-30 wt. percent of (b) C.sub.8 -C.sub.15 Oxo alcohols consisting essentially of a mixture of straight-chain and single methyl branched isomers, said (a) and (b) being in relative proportions so that from about 95-80 wt. percent of said R.sub.1 groups are straight-chain alkyl and correspondingly from 5-20 wt. percent are said branched alkyl, R is a C.sub.1 -C.sub.3 alkyl group, X represents a chloride, bromide or iodide anion, and wherein said mixture of quaternaries is essentially composed of 0-10 wt. percent of compounds of Formula I, 60-85 wt. percent of compounds of Formula II, and 5-25 wt. percent of compounds of Formula III, said mixture being prepared by ammonolysis of a mixture of the corresponding R.sub.1 OH alcohols and subsequent quaternization of the ammonolysis product.
Dependencies are inferred from the claim text.