Two-stage catalysis of engine exhaust
AssigneeCaterpillar Tractor Co.
InventorJohn R. Gladden
Life of this patent
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Abstract
The invention relates to reduction of nitric oxide in exhausts from hydrocarbon burning engines. The nitric oxide is reacted with ammonia over a first catalyst and then the excess ammonia is reacted with oxygen present in the exhaust gas over a second catalyst. The resulting effluent stream has greatly reduced nitric oxide content without having an objectionable content.
Claims3
A method of removing nitric oxide from a hydrocarbon burning engine exhaust stream, the engine operating under varying load conditions from a high load to a low load wherein the exhaust stream temperature varies from a high of about 800.degree. C. to a low of about 200.degree. C., comprising:
- contacting a combusted gas stream comprising nitric oxide and oxygen with ammonia, the contacting over a first catalyst bed having a catalyst comprising a zeolite which catalyzes a reductive reaction of ammonia with nitric oxide, the amount of ammonia from about 0.5 to about 2 times the stoichiometric amount for the reductive reaction of ammonia with nitric oxide, the contacting at a temperature between about 200.degree. C. to about 800.degree. C., the first catalyst bed retaining ammonia when the temperature is above about 315.degree. C. and desorbing a portion of the ammonia at a temperature from about 200.degree. C. to about 315.degree. C., to form an effluent gas stream having oxygen, a reduced amount of nitric oxide content, and having the desorbed portion of ammonia when said contacting is at a temperature from about 200.degree. C. to about 315.degree. C.;
- and
- contacting said effluent gas stream with a second catalyst bed comprising a porous solid carrier having a catalytically active oxidation catalyst metal disposed thereon which is sufficiently active to catalyze the oxidation of the desorbed portion of ammonia to form a substantially nitric oxide free and ammonia free exhaust stream.
Dependencies are inferred from the claim text.