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US 4,181,598 AGranted
Manufacture of lube base stock oil
AssigneeMobil Oil Corporation
InventorsBernard M. Gillespie, Michael S. Sarli, Kenneth W. Smith
Life of this patent
Estimating the term…
Abstract
Lube base stock oil of low pour point and excellent stability is produced from a waxy crude oil fraction by solvent refining, catalytic dewaxing over a zeolite catalyst in the nature of zeolite ZSM-5 and hydrotreating under specified conditions.
Claims14
A process for preparing a high quality lube base stock oil having a pour point of about -25.degree. to +30.degree. F. from waxy crude oil, which comprises:
- extracting a distillate fraction that boils within the range of 450.degree. to 1100.degree. F. or a deasphalted short residuum fraction of said waxy crude with a solvent selective for aromatic hydrocarbons to yield a raffinate from which undesirable compounds have been removed;
- mixing the raffinate with hydrogen and contacting the mixture at a temperature of 500.degree. to 675.degree. F. with a dewaxing catalyst comprising an aluminosilicate zeolite having a silica/alumina ratio of at least about 12 and a constraint index of about 1 to about 12, thereby converting wax contained in the raffinate to lower boiling hydrocarbons;
- cascading the dewaxed raffinate to a hydrotreating zone wherein the dewaxed raffinate is contacted in the presence of hydrogen at a temperature of 425.degree. to 600.degree. F. with a hydrotreating catalyst comprising a hydrogenation component on a non-acidic support;
- and
- topping the dewaxed, hydrotreated raffinate to remove therefrom components of a low molecular weight.
2 more elements
Dependencies are inferred from the claim text.