Method for removal of sulfur deposited on a Claus catalyst
AssigneeStandard Oil Company (Indiana)
InventorsClifton S. Goddin, Jr., John W. Palm
Life of this patent
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AssigneeStandard Oil Company (Indiana)
InventorsClifton S. Goddin, Jr., John W. Palm
Estimating the term…
An improved method of regenerating a low temperature Claus catalyst bed having elemental sulfur deposited on the catalyst involving initially using a moderately hot effluent gas (typically 600.degree. to 650.degree. F.) from the first conventional Claus reactor to warm up the low temperature Claus reactor and remove deposited sulfur and after the outlet temperature of said low temperature reactor reaches a value high enough to decompose COS and CS.sub.2 (typically 600.degree. to 650.degree. F.), supplementing the moderately hot first conventional Claus reactor effluent gas with hot (typically 1000.degree. to 1200.degree. F.) waste heat boiler effluent such that the temperature of the regenerating catalyst bed can be elevated to about 700.degree. F. or higher. The intentional temperature excursion to about 700.degree. F. during catalyst regeneration improves the degree of regeneration of the catalyst bed, promotes higher catalyst activity and extends the catalyst life.
In a process for removal of sulfur from a gaseous stream containing hydrogen sulfide involving first recovering sulfur noncatalytically by burning said gaseous stream in a furnace followed by a waste heat boiler, and then further recovering sulfur catalytically by passing the effluent from the waste heat boiler through a series of Claus reactors with associated liquid sulfur condensers wherein one or more of the lead Claus reactors is operated in a so-called conventional temperature range which is higher than the sulfur dewpoint of the reacting gas and one or more of the following Claus reactors operates in a lower temperature range in which sulfur is strongly adsorbed on the catalyst, and wherein the temperature of the first Claus reactor is maintained sufficiently high to hydrolyze COS and CS.sub.2 and wherein the resulting effluent from the final conventional Claus reactor passes through a low temperature Claus step involving at least two interchangeable reactors, and wherein said conventional Claus effluent at all times passes through at least one of said interchangeable, low temperature reactors to further convert the reactants and condense the sulfur for an interval during which the other said interchangeable, low temperature reactor catalyst is regenerated by vaporization of the deposited sulfur followed by cooling of the sulfur-denuded catalyst, the improvement comprising:
In a process for regenerating a low temperature Claus catalytic reactor having sulfur deposited on the catalyst including the steps of removing said deposited sulfur by contacting said catalyst with a hot gas from the lead conventional Claus reactor upstream from said low temperature Claus catalytic reactor, thus heating said low temperature Claus catalytic reactor to about 600.degree. to 650.degree. F., the improvement comprising:
Dependencies are inferred from the claim text.