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US 4,178,352 AGranted
Synthesis of type Y zeolite
AssigneeW. R. Grace & Co.
InventorsDavid E. W. Vaughan, Grant C. Edwards, Michael G. Barrett
Life of this patent
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Abstract
Type Y zeolite is prepared using a minimum excess of reactants by a method wherein required sodium hydroxide, silica, alumina and water reactants are combined in multi-stage procedure to obtain a uniform fluid reaction slurry. The procedure permits the efficient commercial production of high quality type Y zeolite and minimizes the formation of excess silicate containing by-product effluent.
Claims5
A process for preparing type Y zeolite comprising:
- (a) preparing a slurry of zeolitic nucleation centers having an average particle size below about 0.1 micron, said slurry having the following mol ratio composition:
- 12 to 19 Na.sub.2 O;
- 0.7 to 9 Al.sub.2 O.sub.3 ;
- 12 to 19 SiO.sub.2 ;
- 220 to 900 H.sub.2 O;
- (b) preparing an intermediate reaction mixture by combining the nucleation center composition of step (a) with additional sources of Na.sub.2 O, Al.sub.2 O.sub.3, SiO.sub.2 and H.sub.2 O to obtain a mixture having the following mol ratio composition:
- 2 to 6 Na.sub.2 O;
- 4.5 to 11 SiO.sub.2 ;
- Al.sub.2 O.sub.3 ;
- 30 to 200 H.sub.2 O;
- (c) agitating and heating said intermediate reaction mixture of step (b) at a temperature of from about 30.degree. to 80.degree. C.;
- (d) mixing an acid compound selected from the group comprising mineral acids, aluminum salts of mineral acids and mixtures thereof to the reaction mixture of step (c) to obtain a final reaction mixture having the following mol ratio composition:
- 0.5 to 2.5 Na.sub.n (A);
- 1.2 to 3 Na.sub.2 O;
- 4 to 7.5 SiO.sub.2 ;
- Al.sub.2 O.sub.3 ;
- 40 to 200 H.sub.2 O;
- wherein A is a mineral acid anion and n is the valence of A;
- and
- (e) heating the final reaction mixture of step (d) to a temperature of from about 80.degree. to 150.degree. C. for from about 2 to 40 hours to obtain type Y zeolite.
17 more elements
Dependencies are inferred from the claim text.