Butadiene/acrylonitrile photosensitive, elastomeric polymer compositions for flexographic printing plates
AssigneeE. I. Du Pont de Nemours and Company
InventorStephen Proskow
Life of this patent
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Abstract
Photosensitive, elastomeric compositions containing (1) a high molecular weight butadiene/acrylonitrile copolymer, (2) a low molecular weight butadiene polymer, (3) an ethylenically unsaturated monomer, and (4) a free-radical generating system have outstanding properties as photosensitive coatings for flexographic printing plates. When the combination of high and low molecular weight polymers contains at least about 2% by weight of carboxyl groups, the compositions are processable in aqueous or semiaqueous basic solutions.
Claims18
A photosensitive, elastomeric composition which comprises, based on the total composition,
- (a) 55 to 85% by weight of a high molecular weight butadiene/acrylonitrile copolymer having a number average molecular weight of 20,000 to 75,000, an acrylonitrile content of 10 to 50% by weight, and a carboxyl content of 1 to 15% by weight;
- (b) 5 to 40% by weight of a low molecular weight butadiene polymer having a number average molecular weight of 750 to 10,000, an acrylonitrile content of 0 to 50% by weight, and a carboxyl content of 0 to 15% by weight, with the proviso that the combination of the high molecular weight butadiene/acrylonitrile copolymer and the low molecular weight butadiene polymer contains at least 2% by weight of carboxyl groups;
- (c) 2 to 40% by weight of a nongaseous, ethylenically unsaturated compound containing at least one terminal ethylenic group, said compound being capable of forming a high polymer by free-radical initiated, chain-propagating addition polymerization and being compatible with polymers (a) and (b);
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- (d) 0.001 to 10% by weight of an organic, radiation-sensitive, free-radical generating system, activatable by actinic radiation which initiates polymerization of the unsaturated compound.
Dependencies are inferred from the claim text.