An apparatus comprising a gas-tight casing, spaced electrical elements therein adapted to be subjected to differences of electrical potential, and a gaseous insulator between said elements, said gaseous insulator comprising a synergistic mixture comprising a first component selected from the group of perfluorodimethylcyclobutane, perfluorocyclohexene, hexafluoroazomethane, perfluoromethylcyclohexane, hexafluorobutadiene, perfluoroheptene-1, perfluorobutene-2 and mixtures thereof and a second component selected from the group of SF.sub.6, N.sub.2, CO, CO.sub.2, H.sub.2, C.sub.3 F.sub.8, C.sub.6 F.sub.6 and mixtures thereof.