Zeolite A crystals of uniformly small particle size and the manufacture thereof

A process for the manufacture of zeolite A crystals that are uniform and less than ten microns in size which comprises the steps of:

• (a) preparing zeolite A seed crystals by comminuting zeolite A crystals until seed crystals having a number average particle size of less than about 0.5 .mu.m have been obtained and any cluster crystals that may be present are broken up;
• (b) preparing a sodium aluminum silicate gel containing, on an anhydrous basis, from 26 to 62 mole percent sodium oxide, from 10 to 37 mole percent aluminum oxide, and from 24 to 50 mole percent silicone dioxide, said gel containing from about 88 to 98 mole percent water and being free of particles that would serve as nucleation sites for crystallization;
• (c) uniformly distributing throughout said gel a predetermined quantity of the comminuted zeolite A seed crystals, the quantity being such that said gel is depleted and crystal growth is terminated when said seed crystals have grown to the desired size;
• (d) maintaining said gel at a temperature above about 70.degree. C. until crystallization of the gel is essentially complete;
• and
• (e) separating the zeolite A crystals so formed from the reaction mixture, the number of zeolite A crystals present in the product separated being substantially the same as the number of seed crystals added.