Process for preparing 3,4,3,4-benzophenone-tetracarboxylic dianhydride
AssigneeGulf Research & Development Company
InventorsJohann G. D. Schulz, Anatoli Onopchenko
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Abstract
A process for preparing 3,4,3',4'-benzophenonetetracarboxylic dianhydride which comprises condensing an impure ortho-xylene mixture with acetaldehyde in contact with an acid catalyst to obtain an impure 1,1-bis(3,4-dimethylphenyl)ethane mixture, oxidizing the 1,1-bis(3,4-dimethylphenyl)ethane mixture with nitric acid to obtain a mixture of carboxylic acids, from which by crystallization and dehydration substantially pure 3,4,3',4'-benzophenonetetracarboxylic dianhydride is recovered.
Claims9
A process for preparing 3,4,3',4'-benzophenone-tetracarboxylic dianhydride which comprises condensing an impure ortho-xylene mixture, said impure ortho-xylene mixture containing at least one of meta-xylene, para-xylene, ethylbenzene and cumene, with acetaldehyde in contact with an acid catalyst to obtain an impure 1,1-bis(3,4-dimethylphenyl) ethane mixture, oxidizing the mixture with nitric acid to obtain a mixture of carboxylic acids, from which by crystallization and dehydration, substantially pure 3,4,3',4'-benzophenonetetracarboxylic dianhydride is recovered.
Dependencies are inferred from the claim text.