Process for the preparation of substituted norbornene derivatives
AssigneeThe B. F. Goodrich Company
InventorWolfgang Schneider
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Abstract
Mono or dialkyl substituted norbornenes or cyclic norbornene derivatives are prepared by condensing an appropriate olefin or an ethylenically unsaturated alicyclic compound with dicyclopentadiene or cyclopentadiene at an elevated temperature and pressure in the presence of a chlorinated hydrocarbon solvent.
Claims11
A process for preparing substituted norbornene derivatives of the formula ##STR6## wherein R and R' are independently alkyl or alkylene groups of 1 to 20 carbon atoms provided that the total number of carbon atoms for R and R' is not greater than 20, or R and R' together with the ring carbons to which they are bonded form one or more saturated or unsaturated rings of 6 to 16 carbon atoms, or one of R and R' is hydrogen, said process comprising reacting cyclopentadiene or dicyclopentadiene with an olefin or a cycloolefin at a temperature between 100.degree. and 300.degree. C., at a pressure sufficient to maintain the reaction in liquid phase which is between 50 and 2500 psi and in the presence of a chlorinated or a brominated hydrocarbon solvent.
Dependencies are inferred from the claim text.