Recovery of nitrated compounds using solvent extraction and distillation

A process for separating ethylene glycol dinitrate and nitroglycerin from an aqueous solution thereof comprising:

• (a) contacting said aqueous solution with a solvent comprising ethylene glycol dinitrate for a period of time sufficient to allow extraction of at least a portion of said nitroglycerin into said ethylene glycol dinitrate phase to occur;
• (b) separating the resulting aqueous solution from the resulting ethylene glycol dinitrate phase;
• and
• (c) distilling the resulting aqueous solution from which at least a portion of said nitroglycerin has been extracted at a temperature of from about 50 degrees F. to about 200 degrees F. and at less than atmospheric pressures to thereby separate ethylene glycol dinitrate from the resulting aqueous solution.

A method for separating nitrated esters from a water solution which contains less than about 1 weight percent of nitrated esters of polyalcohols including ethylene glycol dinitrate and nitroglycerin comprising:

• (a) contacting said water solution with a solvent comprising ethylene glycol dinitrate in a volumetric ratio of from about 1:500 to about 1:20 ethylene glycol dinitrate to water solution to thereby extract nitroglycerin from said water solution and into said solvent;
• (b) separating the resulting ethylene glycol dinitrate phase from the resulting water solution;
• (c) passing the resulting water solution into a distillation zone and heating said water to a temperature of from about 50 degrees F. to about 200 degrees F. at a lower than atmospheric pressure in the range of from about 10 to about 500 millimeters of mercury;
• (d) withdrawing a vapor stream comprising said nitrated esters and water from the top of said distillation zone;
• (e) cooling said vapor stream in a cooling zone to condense said water and said nitrated esters to form a water phase and nitrated ester phase;
• (f) separating the resulting condensed water phase from the resulting nitrated ester phase;
• (g) withdrawing the bottom product of said distillation zone which comprises water which is substantially free of said nitrated esters.

A process for separating mixtures of nitrated esters comprising ethylene glycol dinitrate and nitroglycerin from a water solution containing less than about 1 weight percent thereof comprising:

• (a) passing said water solution through an extraction zone in contact with an organic phase of ethylene glycol dinitrate to thereby extract nitroglycerin from said water solution and into said ethylene glycol dinitrate organic phase;
• (b) separating said ethylene glycol dinitrate organic phase from said water solution;
• (c) passing said water solution into a distillation zone and heating said water solution to a temperature of from about 50 degrees F. to about 200 degrees F. at a pressure in the range of from about 10 to about 500 mm of mercury;
• (d) withdrawing a vapor stream from the top of said distillation zone;
• (e) condensing said vapor stream to form a water phase and a nitrated ester phase, said nitrated ester phase consisting essentially of ethylene glycol dinitrate;
• (f) separating said water phase from said nitrated ester phase;
• (g) passing at least a portion of said nitrated ester phase to said extraction zone;
• and
• (h) withdrawing the bottom product of said distillation zone which comprises water which is substantially free of said nitrated esters.