Start-up procedure for reforming with platinum-iridium catalysts
AssigneeExxon Research & Engineering Co.
InventorWilliam B. Lewis
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AssigneeExxon Research & Engineering Co.
InventorWilliam B. Lewis
Estimating the term…
A process wherein a bed of catalyst comprised of platinum and iridium is contacted and pretreated at elevated temperature in a zone, prior to the introduction and contact of the catalyst with feed, with hydrogen, water, halogen, suitably chlorine or hydrogen chloride, or both, and hydrogen sulfide. The bed of catalyst is treated up to, but not significantly beyond the point of breakthrough of hydrogen sulfide from the bed. In its preferred aspects, a bed of fresh or regenerated, reactivated catalyst is wetted with water and an admixture of hydrogen and halogen, preferably hydrogen chloride, saturated or near-saturated with water, is passed through the catalyst bed until the time that the bed has adsorbed, absorbed or has otherwise taken up these components, and they begin to appear in the exit gas. On breakthrough of the hydrogen chloride, the introduction of the hydrogen sulfide gas is continued to breakthrough from the exit side of the bed. Thereafter, feed is introduced at reforming conditions to initiate the reforming operation.
In a process for catalytically reforming a hydrocarbon feed boiling within the gasoline range by contacting said feed at reforming conditions with a bed of catalyst comprised of platinum, iridium and halide components composited with inorganic oxide, the improvement which comprises
A process for catalytically reforming a hydrocarbon feed boiling within the gasoline range by contacting same at reforming conditions with a bed of reactivated catalyst comprised of platinum, iridium and halide and sulfide components composited with inorganic oxide, wherein the catalyst has been deactivated by the deposition of coke deposits thereon, which comprises
Dependencies are inferred from the claim text.