Dihydrooxadiazinones and method for making
AssigneeGeneral Electric Company
InventorGeorge E. Niznik
Life of this patent
Estimating the term…
Abstract
Dihydrooxadiazinones are provided which can be used as blowing agents in various thermoplastic polymeric materials to produce high performance thermoplastic foams. A ketone having at least one .alpha.-hydrogen atom is halogenated and hydroxylated to produce an .alpha.-hydroxyketone. Condensation of the .alpha.-hydroxyketone with an organocarbazate produces the corresponding carboorganooxyhydrazone which is cyclized to a dihydrooxadiazinone.
Claims4
Dihydrooxadiazinones of the formula, ##STR14## where "a" is an integer equal to 1 or 2, and when "a" is 1, R.sup.3 is a monovalent radical and when "a" is 2, R.sup.3 is a divalent radical, and R.sup.3 is selected from the class consisting of aryl radicals selected from the class consisting of tolyl, xylyl and naphthyl, halogenated aryl radicals selected from the class consisting of halophenyl, halotolyl, haloxylyl and halonaphthyl, alkoxy aryl radicals selected from the class consisting of alkoxy phenyl, alkoxy tolyl, alkoxy xylyl and alkoxy naphthyl, nitroaryl radicals selected from the class consisting of nitro phenyl, nitro tolyl, nitro xylyl and nitro naphthyl, sulfoaryl radicals selected from the class consisting of sulfo phenyl, sulfo tolyl, sulfo xylyl and sulfo naphthyl, arylene radicals and halogenated arylene radicals.
Dihydroxadiazinone of the formula, ##STR15## where R.sup.4 is a monovalent C.sub.(6-13) aromatic organic radical selected from aryl radicals selected from the class consisting of tolyl, xylyl and naphthyl, halogenated aryl radicals selected from the class consisting of halo phenyl, halo tolyl, halo xylyl and halo naphthyl, alkoxy aryl radicals, nitro aryl radicals selected from the class consisting of nitro phenyl, nitro tolyl, nitro xylyl and nitro naphthyl and sulfoaryl radicals selected from the class consisting of sulfo phenyl, sulfo tolyl, sulfo xylyl and sulfo naphthyl.
The compound 5-bromophenyl-3,6-dihydro-1,3,4-oxadiazin-2-one.
The compound 5-naphthyl-3,6-dihydro-1,3,4-oxadiazin-2-one.
Dependencies are inferred from the claim text.