Silicone-containing hard contact lens material
AssigneePolymer Technology Corporation
InventorsEdward J. Ellis, Joseph C. Salamone
Life of this patent
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Abstract
An improved contact lens material is formed by a copolymer of a siloxanyl alkyl ester monomer, an itaconate ester and an ester of acrylic or methacrylic acid. The copolymer preferably includes a cross-linking agent and a hydrophilic monomer. Contact lenses made of the mterial can be readily machined and polished into hard contact lenses having excellent dimensional stability but also have extremely high permeability to oxygen.
Claims14
An oxygen permeable, hard, machinable, dimensionally stable, hydrophilic, contact lens material of high transparency consisting essentially of a polymer formed by free radical polymerization from (a) 30-80% by weight of a siloxanyl alkyl ester monomer having the following formula:
- ##STR4## where R.sub.1 is selected from the class of hydrogen or methyl groups, "a" is an integer from one to three, "b" and "c" are integers from zero to two, "d" is an integer from zero to one, A is selected from the class of methyl or phenyl groups, R.sub.2 is selected from the class of methyl or phenyl groups, R.sub.3 and R.sub.4 represent either no group(cyclic ring from "c" to "d") or methyl or phenyl groups,
- (b) 5 to 60% by weight of an itaconate mono- or di-ester,
- (c) 1 to 60 parts by weight of an ester of a C.sub.1 -C.sub.20 monohydric or polyhydric alkanol or phenol and an acid selected from the class consisting essentially of acrylic and methacrylic acid,
- (d) 0.1 to 10% by weight of a cross-linking agent,
- (e) 1 to 20% by weight of a hydrophilic monomer to impart hydrophilic properties to the surface of the contact lens material of this invention.
An oxygen permeable, hard, machinable, dimensionally stable, hydrophilic contact lens consisting essentially of a polymer formed by free radical polymerization from (a) 30-80% by weight of a siloxanyl alkyl ester monomer having the following formula:
- ##STR5## where R.sub.1 is selected from the class of hydrogen or methyl groups, "a" is an integer from one to three, "b" and "c" are integers from zero to two, "d" is an integer from zero to one, A is selected from the class of methyl or phenyl groups, R.sub.2 is selected from the class of methyl or phenyl groups, R.sub.3 and R.sub.4 represent either no group(cyclic ring from "c" to "d") or methyl or phenyl groups,
- (b) 5 to 60% by weight of an itaconate mono- or di-ester,
- (c) 1 to 60 parts by weight of an ester of a C.sub.1 -C.sub.20 monohydric or polyhydric alkanol or phenol and an acid selected from the class consisting essentially of acrylic and methacrylic acid,
- (d) 0.1 to 10% by weight of a cross-linking agent,
- (e) 1 to 20% by weight of a hydrophilic monomer to impart hydrophilic properties to the surface of the contact lens material of this invention.
A hard, oxygen permeable contact lens having good dimensional stability, high transparency and formed by free radical copolymerization of dimethyl itaconate, methyl methacrylate, methacryloxyloxypropyl tris (trimethylsilyl) siloxane, methacrylic acid and tetraethylene glycol dimethacrylate,
- said lens having an oxygen permeability in the range of from 38 to 500 cm.sup.3 mm/cm.sup.2 sec cmHg.times.10.sup.-10 and a Rockwell Hardness value of from 100 to 125 ASTM D-785 R scale.
Dependencies are inferred from the claim text.