Radiation-curable monomers and polymers thereof
AssigneeRohm and Haas Company
InventorDonald A. Winey
Life of this patent
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Abstract
Monoethylenically unsaturated derivatives of substituted benzophenones or acetophenones which are prepared by reaction of such a benzophenone or acetophenone with a vinyl benzyl halide, such as the chloride, are polymerizable to form homopolymers or copolymers e.g. with a wide variety of conventional ethylenically unsaturated monomers, especially monoethylenically unsaturated vinyl or vinylidene monomers. The resulting polymers are sensitive to radiation, such as ultraviolet light, e.g. having a wave length of 2,000 to 5,000 angstroms, and readily cross-link or cure upon exposure to such radiation. Adhesives, binders, coatings, and impregnating compositions are made from the polymers.
Claims10
A monomer selected from the group consisting of those having one of the general formulas:
- ##STR14## wherein R' is methyl or phenyl,
- X is --C(O)O--, and
- Y is a saturated or unsaturated aliphatic group
- (a) of straight or branched chain having 1 to 3 carbon atoms, or
- (b) of cyclic type having 3 to 6 carbon atoms.
Vinylbenzyl benzoylbenzoate.
Vinylbenzyl acetylbenzoate.
Dependencies are inferred from the claim text.