Process for producing a transparent shaped polymeric product
AssigneeJapan Atomic Energy Research Institute
InventorsIsao Kaetsu, Hiroshi Okubo, Fumio Yoshii
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Abstract
This invention provides a process for preparing a transparent polymeric product free from strain and bubbles and having improved physical and chemical properties. The product can be produced from a bis-allylcarbonate-based monomer mixture by cast polymerization for extremely shortened polymerization time.
Claims10
A process for efficiently producing a transparent shaped polymeric product, free from defects such as bubbles and strain, of sufficiently high mechanical strength, surface hardness, weather resistance, and impact resistance to serve as a substitute for inorganic glass, consisting essentially of the steps of:
- mixing
- (A) one or more compounds represented by the formula ##STR4## wherein X is H or CH.sub.3 and l is an integer of from 1 to 4, or a prepolymer thereof, in an amount of from 30 to 80% by weight,
- (B) one or more compounds represented by the formula ##STR5## wherein X is H or CH.sub.3, n is an integer of 2, 3 or 4 and m is an integer of from 3 to 6, or a prepolymer thereof, in an amount of from 70 to 20% by weight based on the total amount of (A) and (B), and
- (C) a radical polymerization catalyst in an amount of from 0.5 to 5 parts by weight per 100 parts of the total amount of (A) and (B);
- pouring the mixture into a cell or mold adapted to cast polymerization;
- irradiating it with light of ionizing radiation at a temperature below room temperature to subject it to cast polymerization;
- and then
- heating it to a temperature ranging from 80.degree. C. to the decomposition temperature of the copolymer to be produced to complete the polymerization.
Dependencies are inferred from the claim text.