US 4,138,434 AGranted

Integrated ammonia-urea producing process, for the production of urea

AssigneeSnamprogetti S.p.A.

InventorsVincenzo Lagana, Francesco Saviano

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Abstract

An improvement of the SNAM ammonia-stripper integrated urea process is disclosed, wherein a gaseous stream obtained by decomposing hydrocarbons is fed to an adiabatic ammonia stripper placed downstream of a carbamate decomposer, the adiabatic stripper also receiving a solution of urea which is rich in ammonia coming from the carbamate decomposer. The thus enriched gaseous stream (NH.sub.3, CO.sub.2, H.sub.2 O) is processed in a CO.sub.2 -absorber (or carbamate reactor) and the process proceeds in the urea synthesis reactor. Recycling and recovery loops are provided between the several reaction and/or decomposing units. Surprisingly, enough, the stripping on NH.sub.3 and CO.sub.2 takes place adiabatically and the drop of the CO.sub.2 partial pressure in the stream fed to the carbamate reactor has no bearing on the efficiency of the carbamate conversion which, according to the current technical teachings, requires an increase of the CO.sub.2 partial pressure.

An integrated process for the production of urea which comprises carrying out in a urea synthesis section the steps of:

(a) feeding a stream of anhydrous ammonia and/or ammonia in aqueous solution and a stream containing ammonium carbamate to a urea-synthesizing reactor so that urea is synthesized therein;
(b) withdrawing a solution of urea containing ammonium carbamate from the urea-synthesizing reactor and feeding said stream to a decomposer wherein about 50% of said ammonium carbamate is decomposed providing ammonia and carbon dioxide;
(c) recycling gaseous ammonia and carbon dioxide from said decomposer to the urea-synthesizing reactor;
(d) withdrawing a solution of urea containing the balance of said ammonium carbamate and enriched with ammonia from said decomposer;
(e) feeding said solution withdrawn from the decomposer in step (d) to an adiabatic stripping column;
(f) feeding a stream of stripping gas consisting of raw ammonia synthesis gases and composed essentially of CO.sub.2, N.sub.2 and H.sub.2 to said stripping column whereby said urea solution is purified and said stripping gas stream is enriched with NH.sub.3, H.sub.2 O and CO.sub.2 ;
(g) recovering purified urea solution from said stripping column;
(h) feeding said enriched stripping gas stream from the stripping column to a CO.sub.2 absorber;
(i) feeding an absorbing liquid comprised of an ammoniacal aqueous solution of ammonium carbonate from an ammonia condenser to the CO.sub.2 absorber so that ammonium carbamate solution is formed in said absorber;
(j) withdrawing ammonium carbamate solution from the CO.sub.2 absorber to provide said stream containing ammonium carbamate fed to said urea synthesizing reactor in step (a);
(k) feeding a stream of non-absorbed synthesis gas rich with ammonia and containing N.sub.2 and H.sub.2 from the CO.sub.2 absorbing column to said ammonia condenser;
(l) feeding an aqueous solution of ammonium carbonate to the ammonia condenser so that the aqueous solution of ammonium carbonate fed to the CO.sub.2 absorber in step (i) is produced;
and
(m) recovering N.sub.2 and H.sub.2 from said ammonia condenser for transmission to an ammonia synthesis section.

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Abstract

Claims4