Process for continuous preparation of fibrous polymer crystals
AssigneeStamicarbon B.V.
InventorsCornelis E. Meihuizen, Albertus J. Pennings, Arie Zwijnenburg
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Abstract
Filament-like polymer crystal fibers are prepared from a solution of a crystallizable polymer, such as polyethylene or polypropylene, in a vessel containing a spinning rotor, preferably having a slightly roughened surface, according to the disclosed invention. The fiber thus formed is taken up and removed at a rate equal to the crystal growth rate. The longitudinal crystal growth rate is of sufficient speed for commercial application while at the same time yielding fibers of outstanding mechanical properties.
Claims17
A process for preparing continuous filament-like crystals of a crystallizable polymer comprising the steps of:
- (a) providing a solution of a crystallizable polymer in a container therefor in contact with a rotating surface;
- (b) rotating said solution while growing a seed crystal of said polymer in the flowing solution and allowing the seed crystal to grow longitudinally with respect to the direction of rotation of said polymer solution;
- and
- (c) removing the thus grown polymer in the form of a continuous filament from the polymer solution at a rate substantially equal to the polymer crystal growth rate, wherein:
- (i) the longitudinal growth takes place at the rotating surface which surface is moving in the direction of the growth of the crystal, and
- (ii) at least about 15 cm of the filament-like crystal thus produced contacts said surface over a length of at least 15 cm thereof.
In a process for preparing continuous filament-like crystals of a crystallizable polymer comprising the steps of:
- (a) providing a solution of a crystallizable polymer in a container therefor in contact with a rotating surface;
- (b) rotating said solution while growing a seed crystal of said polymer in the flowing solution and allowing the seed crystal to grow longitudinally with respect to the direction of rotation of said polymer solution;
- and
- (c) removing the thus grown polymer in the form of a continuous filament from the polymer solution the improvement comprising removing said filament at a rate substantially equal to the polymer crystal growth rate, wherein:
- (i) the longitudinal growth takes place in a Couette flow at a roughened rotor surface generating said flow which surface is moving in the direction of the growth of the crystal, and
- (ii) at least about 15 cm of the filament-like crystal thus produced contacts said surface over a length of at least 15 cm thereof.
A process for preparing continuous polyethylene filament comprising the steps of:
- (a) providing an ethylene solution in a container therefor and in contact with a rotating, roughened surface;
- (b) rotating said surface and polyethylene while growing a seed crystal of said polymer in the flowing polyethylene solution and allowing the seed crystal to grow longitudinally with respect to the direction of rotation of the polyethylene solution;
- and
- (c) removing the thus grown ethylene polymer in the form of a continuous filament from the polymer solution at a rate substantially equal to the polymer crystal growth rate, wherein:
- (i) the longitudinal growth takes place at the rotating surface which surface is roughened and moving in the direction of the growth of the crystal, and
- (ii) at least about 15 cm of the filament-like crystal thus produced contacts said surface over a length of at least 15 cm thereof,
- thereby producing a polyethylene filament having a weight of between about 0.0001 and 0.0012 mg/cm, a tensile strength of greater than 100 kg/mm.sup.2 , an E-modulus of greater than 220 kg/mm.sup.2 and an elongation at break of less than 25 percent.
Dependencies are inferred from the claim text.