Use of water soluble metallo phthalocyanines as oxidation catalysts
AssigneeThe Goodyear Tire & Rubber Company
InventorDavid A. Hutchings
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Abstract
Metallo phthalocyanines which have been rendered water soluble by substituting an alkali metal or alkaline earth metal sulfate or carboxylate salt onto the phthalocyanine structure have been found to be effective catalysts for the oxidation of aromatic compounds having benzylic carbon atoms to form the corresponding hydroperoxides.
Claims5
In the hydroperoxide oxidation of an aromatic compound having the general structural formula (I) ##STR2## wherein R.sup.1 and R.sup.2 are the same or different radicals selected from the group consisting of hydrogen, alkyl radicals containing from 1 to 6 carbon atoms, or R.sup.1 and R.sup.2 can be taken together to form a cycloalkyl ring having from 4 to 7 carbon atoms, A is an aromatic nucleus and R.sup.3 is selected from the group consisting of hydrogen, alkyl radicals having from 1 to 6 carbon atoms, halo radicals, acetyl radicals and methoxy radicals in the presence of a metallo phthalocyanine catalyst at a temperature of from 50.degree. C. to 150.degree. C. at a pressure of from atmospheric pressure to 500 pounds per square inch gauge oxygen partial pressure, the improvement comprising first rendering the metallo phthalocyanine catalyst water soluble by sulfonation using a combination of a material selected from the group consisting of (A) chlorosulfuric acid or (B) sulfuric acid monohydrate combined with fuming sulfuric acid.
Dependencies are inferred from the claim text.