Polyphenylene ether compositions containing rubber modified polystyrene
AssigneeGeneral Electric Company
InventorsArthur Katchman, Gim F. Lee, Jr.
Life of this patent
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Abstract
There are provided high impact strength thermoplastic compositions comprising a polyphenylene ether and a polystyrene resin and rubber of a rubber modified polystryene resin. The compositions include a dispersed elastomeric phase with the dispersed particles having a maximum mean diameter of 2 microns and preferably from about 0.5 to 2 microns. The small elastomeric particles provide molded articles with substantial and unexpected improvements in impact resistance, surface appearance and resistance to aggressive solvent systems in comparison with known compositions having dispersed elastomeric particles of larger than 2 microns in diameter.
Claims19
A high impact thermoplastic composition comprising from 1 to 99% by weight of a polyphenylene ether having the repeating structural formula:
- ##STR3## wherein the oxygen ether atom of one unit is connected to the benzene nucleus of the next adjoining unit, n is a positive integer and is at least 50, and each Q is a monovalent substituent selected from the group consisting of hydrogen, halogen, hydrocarbon radicals free of a tertiary alpha-carbon atom, halohydrocarbon radicals having at least two carbon atoms between the halogen atom and the phenyl nucleus, hydrocarbonoxy radicals and halohydrocarbonoxy radicals having at least two carbon atoms between the halogen atom and the phenyl nucleus, from 99 to 1% of a polystyrene resin, on a rubber-free basis, and from 0.1 to 30% by weight of the total weight of the composition of a rubber, said composition having a dispersed particulate rubber phase in which the particles have a maximum mean diameter of about 2 microns.
A high impact strength thermoplastic composition comprising from 1 to 99% by weight of a polyphenylene ether having the repeating structural formula:
- ##STR4## wherein the oxygen ether atom of one unit is connected to the benzene nucleus of the next adjoining unit, n is a positive integer and is at least 50, and each Q is a monovalent substituent selected from the group consisting of hydrogen, halogen, hydrocarbon radicals free of a tertiary alpha-carbon atom, halohydrocarbon radicals having at least two carbon atoms between the halogen atom and the phenyl nucleus, hydrocarbonoxy radicals and halohydrocarbonoxy radicals having at least two carbon atoms between the halogen atom and the phenyl nucleus and
- (a) a polystyrene resin and a rubber;
- (b) a rubber modified polystyrene resin;
- or
- (c) a mixture of (a) and (b), said polystyrene resin comprising from 99 to 1%, on a rubber-free basis, the composition having a dispersed particulate elastomeric phase in which the particles have a maximum mean diameter of about 2 microns and wherein the elastomeric phase comprises from 0.1 to 30% of the total weight of said composition.
Dependencies are inferred from the claim text.