In a method of establishing electric fields in an ethereal medium for the collection of selected ions, the use adjacent to said medium of a resistive material through which a predetermined electric current flow density is produced by applying different potentials to said material at spaced locations thereon, thereby generating a predetermined electric field in said adjacent medium, the method comprising the controlled selection by spatial focusing of a portion of ions having predetermined physical properties in said medium adjacent said resistive material by the electric field so established and the collection of said portion of ions.