Aluminous quartz ceramics and method
AssigneeCorning Glass Works
InventorDavid G. Grossman
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Abstract
Ceramics comprising a crystal phase composed of a lithium-containing beta-quartz solid solution are treated with a strong acid to selectively remove lithium therefrom by a hydrogen-for-lithium ion exchange process. Heating of the resulting hydrogen-containing crystal phase drives off H.sub.2 O and provides a ceramic product containing a previously unreported hexagonal aluminosilicate crystal phase, denominated aluminous quartz. Stuffed derivatives of aluminous quartz may also be provided.
Claims4
A lithium aluminosilicate glass-ceramic article comprising a principal crystal phase composed of a lithium-containing beta-quartz solid solution, said solid solution containing silica and alumina in a molar ratio (SiO.sub.2 :Al.sub.2 O.sub.3) in the range of about 3.5-7 and lithia in an amount providing a Li.sub.2 O:Al.sub.2 O.sub.3 mole ratio of at least about 0.6, wherein at least part of the beta-quartz solid solution crystal phase has been converted by lithium extraction to an aluminous quartz crystal phase characterized by:
- (a) a composition comprising alumina and silica in a molar ratio (SiO.sub.2 :Al.sub.2 O.sub.3) in the range of about 3.5-7;
- (b) a hexagonal crystal structure;
- and
- (c) an X-ray diffraction pattern comprising intensities (I/I.sub.O) and interplanar spacings (d) conforming substantially to the following:
- ______________________________________ Crystal Plane I/I.sub.o d(A) ______________________________________ 100 19 4.33 101 100 3.38 110 4 2.49 102 4 2.298 200 3 2.156 201 2 2.006 112 11 1.834 202 1 1.686 211 5 1.558 203 7 1.388 ______________________________________
A lithium aluminosilicate glass-ceramic article comprising a principal aluminous quartz crystal phase, produced by the extraction of lithium from a lithium containing beta-quartz solid solution phase, said aluminous quartz crystal phase being characterized by:
- (a) a composition comprising alumina and silica in a molar ratio (SiO.sub.2 :Al.sub.2 O.sub.3) in the range of about 3.5-7;
- (b) a hexagonal crystal structure;
- and
- (c) an X-ray diffraction pattern comprising intensities (I/I.sub.o) and interplanar spacings (d) conforming substantially to the following:
- ______________________________________ Crystal Plane I/I.sub.o d(A) ______________________________________ 100 19 4.33 101 100 3.38 110 4 2.49 102 4 2.298 200 3 2.156 201 2 2.006 112 11 1.834 202 1 1.686 211 5 1.558 203 7 1.388 ______________________________________
A lithium aluminosilicate glass-ceramic article comprising a principal crystal phase composed of a lithium-containing beta-quartz solid solution, said solid solution containing silica and alumina in a molar ratio (SiO.sub.2 :Al.sub.2 O.sub.3) in the range of about 3.5-7, lithia in an amount providing a Li.sub.2 O:Al.sub.2 O.sub.3 mole ratio of at least about 0.6, and at least one oxide stuffing constituent (MO) selected from the group consisting of Na.sub.2 O, K.sub.2 O, MgO, CaO, BaO, SrO, BeO and ZnO, said stuffing constituent being present in a total proportion such that the MO:Al.sub.2 O.sub.3 ratio does not exceed about 0.4, wherein at least part of the beta-quartz solid solution crystal phase has been converted by lithium extraction to a stuffed aluminous quartz crystal phase which:
- (a) comprises alumina and silica in a molar ratio (SiO.sub.2 :Al.sub.2 O.sub.3) in the range of about 3.5-7;
- (b) has a hexagonal crystal structure;
- and
- (c) comprises as a stuffing constituent (MO) at least one Group II metal oxide selected from the group consisting of MgO, CaO, BaO, SrO, BeO, and ZnO, the molar ratio of said stuffing constituent to Al.sub.2 O.sub.3 (MO:Al.sub.2 O.sub.3) not exceeding about 0.4.
A lithium aluminosilicate glass-ceramic article comprising a principal crystal phase composed of stuffed aluminous quartz, said crystal phase being produced by the extraction of lithium from a lithium-containing beta-quartz solid solution phase, and said stuffed aluminous quartz crystal phase;
- (a) comprising alumina and silica in a molar ratio (SiO.sub.2 :Al.sub.2 O.sub.3) in the range of about 3.5-7;
- (b) having a hexagonal crystal structure;
- and
- (c) comprising as a stuffing constituent (MO) at least one Group II metal oxide selected from the group consisting of MgO, CaO, BaO, SrO, BeO, and ZnO, the molar ratio of said stuffing constituent to Al.sub.2 O.sub.3 (MO:Al.sub.2 O.sub.3) not exceeding about 0.4.
Dependencies are inferred from the claim text.