Polyester filament-forming polymer and its method of production
AssigneeMonsanto Company
InventorsDonald L. MacLean, Robert T. Estes
Life of this patent
Estimating the term…
Loading patent…
AssigneeMonsanto Company
InventorsDonald L. MacLean, Robert T. Estes
Estimating the term…
Significantly higher productivity of polyester feed yarn is achieved when the polymer from which the feed yarn is melt spun is chain-branched with multifunctional chain branches having 1-15 microequivalents of reactive branching sites based on one gram of the polymer. This productivity increase (over conventional production employing the same spinnerette in accordance with teachings of the prior art as applied generally to unbranched polymers) may be achieved specifically by spinning a feed yarn (of the same filament denier and draw ratio) at a higher throughput rate at a higher windup speed followed by draw-texturing (at the same draw ratio to the same drawn denier); or by spinning at a higher throughput rate employing the same windup speed a feed yarn of higher denier and draw-ratio followed by draw-texturing at the higher draw ratio to the same drawn denier; or by any combination thereof. The invention herein claimed includes the specific polymer suitable for high throughput spinning as a new composition of matter and its production as a process improvement in the production of drawn polyester yarn.
A polyester filament-forming copolymer suitable for high throughout melt spinning and comprising a polyester polymer and a chain branching agent, the copolymer being chain branched with the chain branching agent to the extent provided by 1-10 microequivalents of available chain branching reactive sites based on one gram of the copolymer.
In the process wherein esters of a dicarboxylic acid and a glycol are polymerized to form a high molecular weight polyester polymer having an intrinsic viscosity of 0.75-0.52 and then melt spun into filaments and taken up at speeds of 2000-6000 ypm (1828-5484 mpm) with controlled cooling between spinning and takeup, and thereafter orientation drawn at about the draw ratio of the filaments, the improvement comprising copolymerizing with said esters a chain branching agent in an amount as to provide 1-15 microequivalents of available chain branching reactive sites based on one gram of the copolymer whereby the draw ratio of the filaments in the drawing step is substantially increased over the draw ratio of a similarly spun unbranched polyester filament.
Dependencies are inferred from the claim text.