Water-in-oil blasting composition
OwnerRobert B. Clayinventor
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OwnerRobert B. Clayinventor
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A blasting composition is disclosed having bulk density and hence explosive energy superior to that of conventional ammonium nitrate fuel oil mixtures, e.g. 94% AN, 6% fuel oil mixtures, but of nearly comparable cost. It comprises two major constituents blended together, namely, (1) about 10 to 40% by weight of a water in oil emulsion which includes aqueous solution of a powerful oxidizer salt as the disperse or inner phase and an oil serving to provide oxygen balance as the external or continuous phase, this emulsion being mixed or blended with (2) a mass of essentially solid particulate oxidizer salt in proportions of 60 to 90% of the total. The emulsion, which may be also a slurry, is mixed to partially but not completely fill the pores or interstices in the solid particulate mass, thereby to increase bulk density, part of the spaces being left unfilled to provide aeration and active sites or "hot spots" to facilitate detonation of the composition by standard detonation devices. Ammonium nitrate preferably constitutes most or all the particulate solid salts; the dissolved salts in the emulsion or slurry preferably comprise a mixture of AN with calcium nitrate to enhance solubility. Other salts such as nitrates, chlorates and perchlorates of ammonium, alkali metals and alkaline earth metals may be added or substituted, at least in part.
A blasting composition consisting essentially of 10 to 40% by weight of a greasy water-in-oil emulsion and 60 to 90% of a substantially undissolved particulate solid oxidizer salt constituent, wherein the emulsion comprises about 3 to 15% by weight of water, 70 to 90% of powerful oxidizer salt comprising ammonium nitrate which may include other powerful oxidizer salts, wherein the solid constituent comprises ammonium nitrate and in which sufficient aeration is entrapped to enhance sensitivity to a substantial degree, and wherein the emulsion component is emulsified by inclusion of 0.1 to 5% by weight, based on the total composition, of an oil-in-water emulsifier to hold the aqueous content in the disperse or internal phase.
An explosive composition which comprises, in combination,
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