Hydroxyalkyl hydroxy-aromatic condensation products as fuel and lubricant additives
AssigneeThe Lubrizol Corporation
InventorCharles Peterson Bryant
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AssigneeThe Lubrizol Corporation
InventorCharles Peterson Bryant
Estimating the term…
Condensation products made by reacting an alpha-hydroxyalkyl hydroxy-aromatic compound also having at least one non-fused hydrocarbyl substituent with at least one olefinic nitrile, carboxylic acid or carboxylic acid derivative are useful as additives for fuels and lubricants. The total number of carbon atoms in the non-fused hydrocarbyl substituents is at least about seven while the alpha-hydroxyalkyl group contains from one to about 36 carbons and the olefinic acid or nitrile reactant usually contains two to about forty carbon atoms. Products made from hydroxymethyl alkyl-substituted phenols and .alpha.,.beta.-olefinic acid derivatives such as maleic anhydride are particularly useful. Similarly useful post-treated products can be made from these condensation products by further reaction with alcohols, amines, metal salts or metals.
A lubricant composition comprising a major amount of at least one lubricating oil and a minor, but engine sludge dispersing, amount of a product made by the process comprising reacting (A) at least one alpha hydroxyalkyl hydroxy aromatic compound of the general formula ##STR22## wherein Ar is a hydrocarbyl aromatic nucleus of 6 to about 30 carbon atoms, each R is a nonfused hydrocarbyl group of about 25 to about 700 carbon atoms, each R' is independently a hydrogen atom, an alkyl group of 1 to 36 carbon atoms, or a halogen-substituted alkyl group of 1 to about 36 carbon atoms, n is 1 to 3 and m is 1 to 5 with the provisos that (i) the total number of carbon atoms in the R' groups does not exceed 36 (ii) where m exceeds 1, one of the R groups can also be a ##STR23## group, with (B) at least one hydrocarbyl, alpha-beta olefinically unsaturated compound selected from the group consisting of C.sub.2 -.sub.40 carboxylic acids and anhydrides, esters, and amides thereof;
Dependencies are inferred from the claim text.