Manufacture of improved fused cast refractory
AssigneeCorning Glass Works
InventorsThomas A. Clishem, Frederick D. Olympia, Leonard W. Pokallus
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AssigneeCorning Glass Works
InventorsThomas A. Clishem, Frederick D. Olympia, Leonard W. Pokallus
Estimating the term…
Basic fused cast refractory with principal crystal phases of periclase and magnesium-spinel is made by adding nonfused oxidic inorganic grog particles to molten mass of the refractory as it is cast into a mold cavity, thereby resulting in increased modulus of rupture at temperature in the range of about 1340.degree.-1500.degree. C. and avoidance of shell formation. Molten mass has a composition consisting essentially (by weight) of 45-78% MgO, 0-30% Cr.sub.2 O.sub.3, 0-35% Al.sub.2 O.sub.3, 0-17% FeO + Fe.sub.2 O.sub.3, at least 82% MgO + Cr.sub.2 O.sub.3 + Al.sub.2 O.sub.3 + FeO + Fe.sub.2 O.sub.3, 1-8% SiO.sub.2, 0-2% CaO + BaO + SrO.sub.2, 0-10% TiO.sub.2 and 0-3% fluorine. Nonfused particles have a loss on ignition at 1000.degree. C. of less than about 0.5% by weight and an aggregate SiO.sub.2 content at least about equal to the SiO.sub.2 content of the molten mass forming the cast refractory. Grog particles are of a size (e.g., within the range of particles passing about 25 mm. sieve openings and retained by about 0.5 mm sieve openings) and in an amount (e.g., about 2.5 to 70% by weight of the cast refractory) sufficient to effect at least partial melting of and penetration into the particles by and resolidification with the cast molten mass so as to form a continuous coherent crystal structure throughout the solidified cast mass wherein discrete grog particles and remnants thereof (if any exist) are not optically identifiable.
The process of manufacturing basic fused cast refractory having principal crystal phases of periclase and magnesium-spinel and analytically consisting essentially of (by weight) of 45-78% MgO, 0-30% Cr.sub.2 O.sub.3, 0-35% Al.sub.2 O.sub.3, 0-17% FeO + Fe.sub.2 O.sub.3, at least 82% MgO + Cr.sub.2 O.sub.3 + Al.sub.2 O.sub.3 + FeO + Fe.sub.2 O.sub.3, 1-8% SiO.sub.2, 0-2% CaO + BaO + SrO, 0-10% TiO.sub.2 and 0-3% fluorine,
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