Monomethine dyestuffs
AssigneeBayer Aktiengesellschaft
InventorHorst Harnisch
Life of this patent
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Abstract
The invention relates to monomethine dyestuffs of the formula ##STR1## wherein Z.sup.1 is alkyl, cycloalkyl, aralkyl or aryl Z.sup.2 is hydrogen or Z.sup.1 Q is CN, COOR.sup.2 or CONR.sup.3 R.sup.4, R.sup.1 u.R.sup.4 is hydrogen or alkyl, R.sup.2 is alkyl, alkenyl, aralkyl, cycloalkyl or aryl and R.sup.3 is alkyl, cycloalkyl, aralkyl, aryl or acyl. The dyestuffs are suitable for the dyeing of natural and synthetic fibers, which are dyed in orange or red shades with high brilliancy.
Claims6
Monomethine dyestuff of the formula ##STR68## wherein T.sup.1 and T.sup.2 independently of one another are unsubstituted C.sub.1 -C.sub.5 -alkyl uninterrupted or interrupted by --O--;
- C.sub.1 -C.sub.4 -alkyl monosubstituted or disubstituted by hydroxyl or chlorine;
- C.sub.1 -C.sub.4 alkyl monosubstituted by bromine, nitrile, C.sub.1 -C.sub.4 -alkoxycarbonyl, aminocarbonyl, phenoxy, benzyloxy, cyclohexyloxy, cyclohexyl, C.sub.1 -C.sub.4 -alkoxycarbonyloxy, C.sub.1 -C.sub.4 -alkylcarbonyloxy, acetylamino, C.sub.1 -C.sub.4 -alkylsulphonylamino, aminocarbonyloxy, di-(C.sub.1 -C.sub.4 -alkyl) amino, carboxyl or sulpho;
- cyclohexyl;
- phenyl-C.sub.1 -C.sub.3 -alkyl;
- hydrogen;
- C.sub.1 -C.sub.4 -alkyl uninterrupted or interrupted by --O-- and substituted by benzyloxycarbonyl, phenoxycarbonyl, phenoxy substituted by 1-5 chlorine atoms, C.sub.1 -C.sub.4 -alkylsulphonyl, benzylsulphonyl, phenylsulphonyl, benzylcarbonyloxy, benzoyloxy, C.sub.1 -C.sub.4 -alkoxycarbonyl-benzoyloxy, phenoxycarbonyloxy, tri-(C.sub.1 -C.sub.4 -alkyl) ammonium, benzoylamino, phenylaminocarbonylamino, phenylsulphonylamino or toluenesulphonylamino;
- or ethylene or 1,3-propylene unsubstituted or substituted with C.sub.1 -C.sub.3 -alkyl and connected to the 6- or 8-position of the coumarin ring;
- T.sup.3 is hydrogen or methyl;
- Q' is CN or COOR;
- R is C.sub.1 -C.sub.6 -alkyl;
- C.sub.1 -C.sub.4 -alkyl substituted by hydroxyl, C.sub.1 -C.sub.4 -alkoxy, nitrile, chlorine, bromine, benzyloxy, phenoxy, cyclohexyloxy, di-(C.sub.1 -C.sub.4 -alkyl)amino, N-tri-(C.sub.1 -C.sub.4 -alkyl) ammonium, or phenyl;
- or is allyl, cyclohexyl or phenyl;
- and
- the ring A' is unsubstituted or substituted by methoxy, methyl or chloromethyl.
Monomethine dyestuff of the formula ##STR69##
Monomethine dyestuff of the formula ##STR70##
Dependencies are inferred from the claim text.