Stabilizer mixtures

A stabilized resin comprising a polybutadiene, and a stabilizing amount of a mixture of an oxetanyl free neutral ester of phosphorous acid and an oxetane compound having a formula selected from ##STR13## wherein each of the six groups R independently represents a hydrogen atom or a (C.sub.1 -C.sub.18)-alkyl, (C.sub.3 -C.sub.12)-cycloalkyl, (C.sub.6 -C.sub.15)-aryl, (C.sub.7 -C.sub.15)-aralkyl group or a group of the formula CH.sub.2 O-R.sup.1 in which

• R.sup.1 represents a hydrogen atom, or a (C.sub.1 -C.sub.18)-alkyl, (C.sub.3 -C.sub.12)-cycloalkyl, (C.sub.6 -C.sub.15)-aryl, (C.sub.7 -C.sub.15)-aralkyl, an acyl radical of a mono- or polybasic carboxylic acid, or the ester residue of an inorganic acid selected from the group consisting of boric, silicic, alkylboric, arylboric, stannoic, stibonic, orthophosphoric, pyrophosphoric, polyphosphoric, alkanephosphonic, arylphosphonic, dialkylphosphinic acids and of diarylphosphinic acids, and ##STR14## wherein R.sub.1 is H, C.sub.1 -C.sub.18 -alkyl, C.sub.1 -C.sub.18 -hydroxyalkyl, C.sub.6 -C.sub.15 -aryl, (C.sub.6 -C.sub.15 -aryl)-oxymethyl, C.sub.7 -C.sub.15 -aralkyl or (C.sub.7 -C.sub.15 -aralkyl)-oxymethyl,
• R.sub.2 is H, C.sub.1 -C.sub.18 -alkyl, C.sub.6 -C.sub.15 -aryl, C.sub.7 -C.sub.15 -aralkyl or the acyl radical of a monobasic or polybasic carboxylic acid
• or the ester residue of an inorganic acid selected from the group consisting of boric, silicic, alkylboric, arylboric, stannoic, stibonic, orthophosphoric, pyrophosphoric, polyphosphoric, alkanephosphonic, arylphosphonic, dialkylphosphinic acids and of diarylphosphinic acids, and
• n is an integer which has a value of 1 or is equal to the acid functionality of the acid from which the acid radical R.sub.2 is derived, said mixture containing from 2 to 10 oxetane groups per phosphorus atom.

A stabilized resin comprising high or low pressure polyethylene, and a stabilizing amount of a mixture of an oxetanyl free neutral ester of phosphorous acid and an oxetane compound having a formula selected from ##STR15## wherein each of the six groups R independently represents a hydrogen atom or a (C.sub.1 -C.sub.18)-alkyl, (C.sub.3 -C.sub.12)-cycloalkyl, (C.sub.6 -C.sub.15)-aryl, (C.sub.7 -C.sub.15)-aralkyl group or a group of the formula CH.sub.2 O-R.sup.1 in which

• R.sup.1 represents a hydrogen atom, or a (C.sub.1 -C.sub.18)-alkyl, (C.sub.3 -C.sub.12)-cycloalkyl, (C.sub.6 -C.sub.15)-aryl, (C.sub.7 -C.sub.15)-aralkyl, an acyl radical of a mono- or polybasic carboxylic acid, or the ester residue of an inorganic acid selected from the group consisting of boric, silicic, alkylboric, arylboric, stannoic, stibonic, orthophosphoric, pyrophosphoric, polyphosphoric, alkanephosphonic, arylphosphonic, dialkylphosphinic acids and of diarylphosphinic acids, and ##STR16## wherein R.sub.1 is H, C.sub.1 -C.sub.18 -alkyl, C.sub.1 -C.sub.18 -hydroxyalkyl, C.sub.6 -C.sub.15 -aryl, (C.sub.6 -C.sub.15 -aryl)-oxymethyl, C.sub.7 -C.sub.15 -aralkyl or (C.sub.7 -C.sub.15 -aralkyl)-oxymethyl,
• R.sub.2 is H, C.sub.1 -C.sub.18 -alkyl, C.sub.6 -C.sub.15 -aryl, C.sub.7 -C.sub.15 -aralkyl or the acyl radical of a monobasic or polybasic carboxylic acid
• or the ester residue of an inorganic acid selected from the group consisting of boric, silicic, alkylboric, arylboric, stannoic, stibonic, orthophosphoric, pyrophosphoric, polyphosphoric, alkanephosphonic, arylphosphonic, dialkylphosphinic acids and of diarylphosphinic acids, and
• n is an integer which has a value of 1 or is equal to the acid functionality of the acid from which the acid radical R.sub.2 is derived, said mixture containing from 2 to 10 oxetane groups per phosphorus atom.

A stabilized resin comprising polypropylene, and a stabilizing amount of a mixture of an oxetanyl free neutral ester of phosphorous acid and an oxetane compound having a formula selected from ##STR17## wherein each of the six groups R independently represents a hydrogen atom or a (C.sub.1 -C.sub.18)-alkyl, (C.sub.3 -C.sub.12)-cycloalkyl, (C.sub.6 -C.sub.15)-aryl, (C.sub.7 -C.sub.15)-aralkyl group or a group of the formula CH.sub.2 O-R.sup.1 in which

• R.sup.1 represents a hydrogen atom, or a (C.sub.1 -C.sub.18)-alkyl, (C.sub.3 -C.sub.12)-cycloalkyl, (C.sub.6 -C.sub.15)-aryl, (C.sub.7 -C.sub.15)-aralkyl, an acyl radical of a mono- or polybasic carboxylic acid, or the ester residue of an inorganic acid selected from the group consisting of boric, silicic, alkylboric, arylboric, stannoic, stibonic, orthophosphoric, pyrophosphoric, polyphosphoric, alkanephosphonic, arylphosphonic, dialkylphosphinic acids and of diarylphosphinic acids, and ##STR18## wherein R.sub.1 is H, C.sub.1 -C.sub.18 -alkyl, C.sub.1 -C.sub.18 -hydroxyalkyl, C.sub.6 -C.sub.15 -aryl, (C.sub.6 -C.sub.15 -aryl)-oxymethyl, C.sub.7 -C.sub.15 -aralkyl or (C.sub.7 -C.sub.15 -aralkyl)-oxymethyl,
• R.sub.2 is H, C.sub.1 -C.sub.18 -alkyl, C.sub.6 -C.sub.15 -aryl, C.sub.7 -C.sub.15 -aralkyl or the acyl radical of a monobasic or polybasic carboxylic acid
• or the ester residue of an inorganic acid selected from the group consisting of boric, silicic, alkylboric, arylboric, stannoic, stibonic, orthophosphoric, pyrophosphoric, polyphosphoric, alkanephosphonic, arylphosphonic, dialkylphosphinic acids and of diarylphosphinic acids, and
• n is an integer which has a value of 1 or is equal to the acid functionality of the acid from which the acid radical R.sub.2 is derived, said mixture containing from 2 to 10 oxetane groups per phosphorus atom.

A stabilized resin comprising polyacrylonitrile, and a stabilizing amount of a mixture of an oxetanyl free neutral ester of phosphorous acid and an oxetane compound having a formula selected from ##STR19## wherein each of the six groups R independently represents a hydrogen atom or a (C.sub.1 -C.sub.18)-alkyl, (C.sub.3 -C.sub.12)-cycloalkyl, (C.sub.6 -C.sub.15)-aryl, (C.sub.7 -C.sub.15)-aralkyl group or a group of the formula CH.sub.2 O-R.sup.1 in which

• R.sup.1 represents a hydrogen atom, or a (C.sub.1 -C.sub.18)-alkyl, (C.sub.3 -C.sub.12)-cycloalkyl, (C.sub.6 -C.sub.15)-aryl, (C.sub.7 -C.sub.15)-aralkyl, an acyl radical of a mono- or polybasic carboxylic acid, or the ester residue of an inorganic acid selected from the group consisting of boric, silicic, alkylboric, arylboric, stannoic, stibonic, orthophosphoric, pyrophosphoric, polyphosphoric, alkanephosphonic, arylphosphonic, dialkylphosphinic acids and of diarylphosphinic acids, and ##STR20## wherein R.sub.1 is H, C.sub.1 -C.sub.18 -alkyl, C.sub.1 -C.sub.18 -hydroxyalkyl, C.sub.6 -C.sub.15 -aryl, (C.sub.6 -C.sub.15 -aryl)-oxymethyl, C.sub.7 -C.sub.15 -aralkyl or (C.sub.7 -C.sub.15 -aralkyl)-oxymethyl,
• R.sub.2 is H, C.sub.1 -C.sub.18 -alkyl, C.sub.6 -C.sub.15 -aryl, C.sub.7 -C.sub.15 -aralkyl or the acyl radical of a monobasic or polybasic carboxylic acid
• or the ester residue of an inorganic acid selected from the group consisting of boric, silicic, alkylboric, arylboric, stannoic, stibonic, orthophosphoric, pyrophosphoric, polyphosphoric, alkanephosphonic, arylphosphonic, dialkylphosphinic acids and of diarylphosphinic acids, and
• n is an integer which has a value of 1 or is equal to the acid functionality of the acid from which the acid radical R.sub.2 is derived, said mixture containing from 2 to 10 oxetane groups per phosphorus atom.

A stabilized resin comprising an acrylonitrile-butadiene-styrene copolymer, and a stabilizing amount of a mixture of an oxetanyl free neutral ester of phosphorous acid and an oxetane compound having a formula selected from ##STR21## wherein each of the six groups R independently represents a hydrogen atom or a (C.sub.1 -C.sub.18)-alkyl, (C.sub.3 -C.sub.12)-cycloalkyl, (C.sub.6 -C.sub.15)-aryl, (C.sub.7 -C.sub.15)-aralkyl group or a group of the formula CH.sub.2 O-R.sup.1 in which

• R.sup.1 represents a hydrogen atom, or a (C.sub.1 -C.sub.18)-alkyl, (C.sub.3 -C.sub.12)-cycloalkyl, (C.sub.6 -C.sub.15)-aryl, (C.sub.7 -C.sub.15)-aralkyl, an acyl radical of a mono- or polybasic carboxylic acid, or the ester residue of an inorganic acid selected from the group consisting of boric, silicic, alkylboric, arylboric, stannoic, stibonic, orthophosphoric, pyrophosphoric, polyphosphoric, alkanephosphonic, arylphosphonic, dialkylphosphinic acids and of diarylphosphinic acids, and ##STR22## wherein R.sub.1 is H, C.sub.1 -C.sub.18 -alkyl, C.sub.1 -C.sub.18 -hydroxyalkyl, C.sub.6 -C.sub.15 -aryl, (C.sub.6 -C.sub.15 -aryl)-oxymethyl, C.sub.7 -C.sub.15 -aralkyl or (C.sub.7 -C.sub.15 -aralkyl)-oxymethyl,
• R.sub.2 is H, C.sub.1 -C.sub.18 -alkyl, C.sub.6 -C.sub.15 -aryl, C.sub.7 -C.sub.15 -aralkyl or the acyl radical of a monobasic or polybasic carboxylic acid
• or the ester residue of an inorganic acid selected from the group consisting of boric, silicic, alkylboric, arylboric, stannoic, stibonic, orthophosphoric, pyrophosphoric, polyphosphoric, alkanephosphonic, arylphosphonic, dialkylphosphinic acids and of diarylphosphinic acids, and
• n is an integer which has a value of 1 or is equal to the acid functionality of the acid from which the acid radical R.sub.2 is derived, said mixture containing from 2 to 10 oxetane groups per phosphorus atom.

A stabilized resin comprising a polyvinyl chloride, and a stabilizing amount of a mixture of an oxetanyl free neutral ester of phosphorous acid and an oxetane compound having a formula selected from ##STR23## wherein each of the six groups R independently represents a hydrogen atom or a (C.sub.1 -C.sub.18)-alkyl, (C.sub.3 -C.sub.12)-cycloalkyl, (C.sub.6 -C.sub.15)-aryl, (C.sub.7 -C.sub.15)-aralkyl group or a group of the formula CH.sub.2 O-R.sup.1 in which

• R.sup.1 represents a hydrogen atom, or a (C.sub.1 -C.sub.18)-alkyl, (C.sub.3 -C.sub.12)-cycloalkyl, (C.sub.6 -C.sub.15)-aryl, (C.sub.7 -C.sub.15)-aralkyl, an acyl radical of a mono- or polybasic carboxylic acid, or the ester residue of an inorganic acid selected from the group consisting of boric, silicic, alkylboric, arylboric, stannoic, stibonic, orthophosphoric, pyrophosphoric, polyphosphoric, alkanephosphonic, arylphosphonic, dialkylphosphinic acids and of diarylphosphinic acids, and ##STR24## wherein R.sub.1 is H, C.sub.1 -C.sub.18 -alkyl, C.sub.1 -C.sub.18 -hydroxyalkyl, C.sub.6 -C.sub.15 -aryl, (C.sub.6 -C.sub.15 -aryl)-oxymethyl, C.sub.7 -C.sub.15 -aralkyl or (C.sub.7 -C.sub.15 -aralkyl)-oxymethyl,
• R.sub.2 is H, C.sub.1 -C.sub.18 -alkyl, C.sub.6 -C.sub.15 -aryl, C.sub.7 -C.sub.15 -aralkyl or the acyl radical of a monobasic or polybasic carboxylic acid
• or the ester residue of an inorganic acid selected from the group consisting of boric, silicic, alkylboric, arylboric, stannoic, stibonic, orthophosphoric, pyrophosphoric, polyphosphoric, alkanephosphonic, arylphosphonic, dialkylphosphinic acids and of diarylphosphinic acids, and
• n is an integer which has a value of 1 or is equal to the acid functionality of the acid from which the acid radical R.sub.2 is derived, said mixture containing from 2 to 10 oxetane groups per phosphorus atom.

A stabilized resin comprising an addition polymer, and a stabilizing amount of a mixture of an oxetanyl free neutral ester of phosphorous acid and an oxetane compound having a formula selected from ##STR25## wherein each of the six groups R independently represents a hydrogen atom or a (C.sub.1 -C.sub.18)-alkyl, (C.sub.3 -C.sub.12)-cycloalkyl, (C.sub.6 -C.sub.15)-aryl, (C.sub.7 -C.sub.15)-aralkyl group or a group of the formula CH.sub.2 O-R.sup.1 in which

• R.sup.1 represents a hydrogen atom, or a (C.sub.1 -C.sub.18)-alkyl, (C.sub.3 -C.sub.12)-cycloalkyl, (C.sub.6 -C.sub.15)-aryl, (C.sub.7 -C.sub.15)-aralkyl, an acyl radical of a mono- or polybasic carboxylic acid, or the ester residue of an inorganic acid selected from the group consisting of boric, silicic, alkylboric, arylboric, stannoic, stibonic, orthophosphoric, pyrophosphoric, polyphosphoric, alkanephosphonic, arylphosphonic, dialkylphosphinic acids and of diarylphosphinic acids, and ##STR26## wherein R.sub.1 is H, C.sub.1 -C.sub.18 -alkyl, C.sub.1 -C.sub.18 -hydroxyalkyl, C.sub.6 -C.sub.15 -aryl, (C.sub.6 -C.sub.15 -aryl)-oxymethyl, C.sub.7 -C.sub.15 -aralkyl or (C.sub.7 -C.sub.15 -aralkyl)-oxymethyl,
• R.sub.2 is H, C.sub.1 -C.sub.18 -alkyl, C.sub.6 -C.sub.15 -aryl, C.sub.7 -C.sub.15 -aralkyl or the acyl radical of a monobasic or polybasic carboxylic acid
• or the ester residue of an inorganic acid selected from the group consisting of boric, silicic, alkylboric, arylboric, stannoic, stibonic, orthophosphoric, pyrophosphoric, polyphosphoric, alkanephosphonic, arylphosphonic, dialkylphosphinic acids and of diarylphosphinic acids, and
• n is an integer which has a value of 1 or is equal to the acid functionality of the acid from which the acid radical R.sub.2 is derived, said mixture containing from 2 to 10 oxetane groups per phosphorus atom.

A stabilized resin comprising a polyphenylene oxide, and a stabilizing amount of a mixture of an oxetanyl free neutral ester of phosphorous acid and an oxetane compound having a formula selected from ##STR27## wherein each of the six groups R independently represents a hydrogen atom or a (C.sub.1 -C.sub.18)-alkyl, (C.sub.3 -C.sub.12)-cycloalkyl, (C.sub.6 -C.sub.15)-aryl, (C.sub.7 -C.sub.15)-aralkyl group or a group of the formula CH.sub.2 O-R.sup.1 in which

• R.sup.1 represents a hydrogen atom, or a (C.sub.1 -C.sub.18)-alkyl, (C.sub.3 -C.sub.12)-cycloalkyl, (C.sub.6 -C.sub.15)-aryl, (C.sub.7 -C.sub.15)-aralkyl, an acyl radical of a mono- or polybasic carboxylic acid, or the ester residue of an inorganic acid selected from the group consisting of boric, silicic, alkylboric, arylboric, stannoic, stibonic, orthophosphoric, pyrophosphoric, polyphosphoric, alkanephosphonic, arylphosphonic, dialkylphosphinic acids and of diarylphosphinic acids, and ##STR28## wherein R.sub.1 is H, C.sub.1 -C.sub.18 -alkyl, C.sub.1 -C.sub.18 -hydroxyalkyl, C.sub.6 -C.sub.15 -aryl, (C.sub.6 -C.sub.15 -aryl)-oxymethyl, C.sub.7 -C.sub.15 -aralkyl or (C.sub.7 -C.sub.15 -aralkyl)-oxymethyl,
• R.sub.2 is H, C.sub.1 -C.sub.18 -alkyl, C.sub.6 -C.sub.15 -aryl, C.sub.7 -C.sub.15 -aralkyl or the acyl radical of a monobasic or polybasic carboxylic acid
• or the ester residue of an inorganic acid selected from the group consisting of boric, silicic, alkylboric, arylboric, stannoic, stibonic, orthophosphoric, pyrophosphoric, polyphosphoric, alkanephosphonic, arylphosphonic, dialkylphosphinic acids and of diarylphosphinic acids, and
• n is an integer which has a value of 1 or is equal to the acid functionality of the acid from which the acid radical R.sub.2 is derived, said mixture containing from 2 to 10 oxetane groups per phosphorus atom.

A stabilized resin comprising a polyamide and a stabilizing amount of a mixture of an oxetanyl free neutral ester of phosphorous acid and an oxetane compound having a formula selected from ##STR29## wherein each of the six groups R independently represents a hydrogen atom or a (C.sub.1 -C.sub.18)-alkyl, (C.sub.3 -C.sub.12)-cycloalkyl, (C.sub.6 -C.sub.15)-aryl, (C.sub.7 -C.sub.15)-aralkyl group or a group of the formula CH.sub.2 O-R.sup.1 in which

• R.sup.1 represents a hydrogen atom, or a (C.sub.1 -C.sub.18)-alkyl, (C.sub.3 -C.sub.12)-cycloalkyl, (C.sub.6 -C.sub.15)-aryl, (C.sub.7 -C.sub.15)-aralkyl, an acyl radical of a mono- or polybasic carboxylic acid, or the ester residue of an inorganic acid selected from the group consisting of boric, silicic, alkylboric, arylboric, stannoic, stibonic, orthophosphoric, pyrophosphoric, polyphosphoric, alkanephosphonic, arylphosphonic, dialkylphosphinic acids and of diarylphosphinic acids, and ##STR30## wherein R.sub.1 is H, C.sub.1 -C.sub.18 -alkyl, C.sub.1 -C.sub.18 -hydroxyalkyl, C.sub.6 -C.sub.15 -aryl, (C.sub.6 -C.sub.15 -aryl)-oxymethyl, C.sub.7 -C.sub.15 -aralkyl or (C.sub.7 -C.sub.15 -aralkyl)-oxymethyl,
• R.sub.2 is H, C.sub.1 -C.sub.18 -alkyl, C.sub.6 -C.sub.15 -aryl, C.sub.7 -C.sub.15 -aralkyl or the acyl radical of a monobasic or polybasic carboxylic acid
• or the ester residue of an inorganic acid selected from the group consisting of boric, silicic, alkylboric, arylboric, stannoic, stibonic, orthophosphoric, pyrophosphoric, polyphosphoric, alkanephosphonic, arylphosphonic, dialkylphosphinic acids and of diarylphosphinic acids, and
• n is an integer which has a value of 1 or is equal to the acid functionality of the acid from which the acid radical R.sub.2 is derived, said mixture containing from 2 to 10 oxetane groups per phosphorus atom.

A stabilized resin comprising a condensation polymer, and a stabilizing amount of a mixture of an oxetanyl free neutral ester of phosphorous acid and an oxetane compound having a formula selected from ##STR31## wherein each of the six groups R independently represents a hydrogen atom or a (C.sub.1 -C.sub.18)-alkyl, (C.sub.3 -C.sub.12)-cycloalkyl, (C.sub.6 -C.sub.15)-aryl, (C.sub.7 -C.sub.15)-aralkyl group or a group of the formula CH.sub.2 O-R.sup.1 in which

• R.sup.1 represents a hydrogen atom, or a (C.sub.1 -C.sub.18)-alkyl, (C.sub.3 -C.sub.12)-cycloalkyl, (C.sub.6 -C.sub.15)-aryl, (C.sub.7 -C.sub.15)-aralkyl, an acyl radical of a mono- or polybasic carboxylic acid, or the ester residue of an inorganic acid selected from the group consisting of boric, silicic, alkylboric, arylboric, stannoic, stibonic, orthophosphoric, pyrophosphoric, polyphosphoric, alkanephosphonic, arylphosphonic, dialkylphosphinic acids and of diarylphosphinic acids, and ##STR32## wherein R.sub.1 is H, C.sub.1 -C.sub.18 -alkyl, C.sub.1 -C.sub.18 -hydroxyalkyl, C.sub.6 -C.sub.15 -aryl, (C.sub.6 -C.sub.15 -aryl)-oxymethyl, C.sub.7 -C.sub.15 -aralkyl or (C.sub.7 -C.sub.15 -aralkyl)-oxymethyl,
• R.sub.2 is H, C.sub.1 -C.sub.18 -alkyl, C.sub.6 -C.sub.15 -aryl, C.sub.7 -C.sub.15 -aralkyl or the acyl radical of a monobasic or polybasic carboxylic acid
• or the ester residue of an inorganic acid selected from the group consisting of boric, silicic, alkylboric, arylboric, stannoic, stibonic, orthophosphoric, pyrophosphoric, polyphosphoric, alkanephosphonic, arylphosphonic, dialkylphosphinic acids and of diarylphosphinic acids, and
• n is an integer which has a value of 1 or is equal to the acid functionality of the acid from which the acid radical R.sub.2 is derived, said mixture containing from 2 to 10 oxetane groups per phosphorus atom.