Melt processable thermotropic wholly aromatic polyester
AssigneeCelanese Corporation
InventorsGordon W. Calundann, Herbert L. Davis, Frederick J. Gorman, Robert M. Mininni
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AssigneeCelanese Corporation
InventorsGordon W. Calundann, Herbert L. Davis, Frederick J. Gorman, Robert M. Mininni
Estimating the term…
A wholly aromatic polyester is provided which has been found to be highly amenable to melt extrusion to yield high performance fibers. Such fibers following thermal treatment exhibit high tenacity and tensile modulus properties which are well retained at elevated temperatures while exhibiting a low degree of shrinkage. Unlike wholly aromatic polyesters normally encountered in the prior art, the polymer of the present invention is not intractable and may be melt extruded with ease at temperatures below approximately 300.degree. C., and preferably below approximately 280.degree. C. The aromatic polyester of the present invention consists essentially of recurring units (a) p-oxybenzoyl moiety, (b) 2,6-dicarboxynaphthalene moiety, (c) symmetrical dioxy aryl moiety (as defined), and (d) isophthaloyl moiety and/or metal-dioxy phenylene moiety, and is free of units which possess ring substitution. The wholly aromatic polyester of the present invention forms an atypical thermotropic melt phase which is exhibited in the absence of ring substitution at a relatively low temperature which facilitates fiber formation with ease. The wholly aromatic polyester of the present invention following melt spinning and thermal treatment commonly can exhibit an average single filament tenacity of at least 15 grams per denier, and an average single filament tensile modulus of at least 300 grams per denier.
An improved melt processable wholly aromatic polyester capable of forming a thermotropic melt phase at a temperature below approximately 300.degree. C. consisting essentially of the recurring moieties I, II, III, and IV wherein:
An improved melt processable wholly aromatic polyester capable of forming a thermotropic melt phase at a temperature below approximately 300.degree. C. consisting of the recurring moieties I, II, III, and IV wherein:
An improved melt processable wholly aromatic polyester capable of forming a thermotropic melt phase at a temperature below approximately 300.degree. C. consisting essentially of the recurring moieties I, II, III, and IV wherein:
An improved melt processable wholly aromatic polyester capable of forming a thermotropic melt phase at a temperature below approximatey 300.degree. C. consisting of the recurring moieties I, II, III, and IV wherein:
Dependencies are inferred from the claim text.