Crosslinkable polymeric compounds
AssigneeCiba-Geigy Corporation
InventorsNiklaus Baumann, Hans Zweifel, Marcus Baumann, John Sidney Waterhouse
Life of this patent
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Abstract
The invention relates to organic polymers which can be crosslinked under the action of light and which are suitable for carrying out photomechanical processes. These polymers are photochemically considerably more sensitive than known comparable polymers and their sensitivity can additionally also be further increased by means of a combination with sensitizers. The molecular weight is at least 1,000. The polymers contain, as light-sensitive groups, groups of the formula I ##STR1## wherein R and R.sub.1 independently of one another denote alkyl groups with at most 4 C atoms, or R and R.sub.1 conjointly denote the remaining part of a 5-membered to 6-membered carbocyclic ring.
Claims12
A polymer, which can be crosslinked under the action of electromagnetic waves, having a molecular weight between 1000 and 1,000,000 as measured by viscometry of a 2% by weight solution in cyclohexanone or of a 0.5% by weight solution in N,N-dimethylformamide, which is characterized by a structural formula comprising a multiplicity of molecular chain members selected from the group consisting of ##STR66## in which MI denotes the maleimido group of formula I ##STR67## wherein R and R.sub.1 independently of one another denote alkyl of 1 to 4 carbon atoms, or R and R.sub.1 conjointly denote the remaining part of a five-membered to six-membered carbocyclic ring, Y.sub.2 denotes an aliphatic, cycloaliphatic, carbocyclicaromatic, araliphatic, heterocyclic-aliphatic or hetero-cyclicaromatic radical containing, in each case, a total of at most up to 18 carbon atoms, and in which Y.sub.1 has the same definition as Y.sub.2 or represents the grouping ##STR68## Y.sub.3 has the same definition as Y.sub.2 or represents the grouping ##STR69## Y.sub.4 has the same definition as Y.sub.2 or represents the grouping ##STR70## Y.sub.5 has the same definition as Y.sub.2 or represents the grouping
- --CO--Y.sub.2
- Y.sub.6 has the same definition as Y.sub.2, and Y.sub.7 has the same definition as Y.sub.2, R.sub.3 denotes hydrogen or alkyl with 1 to 6 carbon atoms, R.sub.4 denotes hydrogen or alkyl, R.sub.5, R.sub.6 and R.sub.7 independently of one another denote hydrogen, halogen, cyano, alkyl, aryl or aralkyl, and R.sub.8 denotes hydrogen, carboxyl or --COO(CH.sub.2).sub.z CH.sub.3 (z = 0 to 18).
Dependencies are inferred from the claim text.