Regeneration of supported ruthenium catalyst
AssigneeICI Americas Inc.
InventorsWalter M. Kruse, Leon W. Wright
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Abstract
Regeneration of supported ruthenium catalysts. A supported ruthenium catalyst which has been used for conversion of carbohydrates to polyhydric alcohols is regenerated by contacting the catalyst with an aqueous solution of a mineral acid, such as sulfuric, hydrochloric, or phosphoric acid. Dilute acids, e.g., 0.01 N to 0.5 N, are preferred.
Claims15
A process for regenerating a supported ruthenium catalyst which has been used to convert a carbohydrate in an aqueous medium at a pH of about 3 to about 7.5 to a polyhydric alcohol or mixture of polyhydric alcohols in the presence of hydrogen under elevated pressure at a temperature in the range of about 100.degree. C. to about 200.degree. C., said process comprising separating said catalyst from the reaction medium and contacting said catalyst with a dilute aqueous solution of a water soluble acid, the concentration of said aqueous solution of said water soluble acid being such as to effectively regenerate said catalyst without dissolving an appreciable portion of the support.
Dependencies are inferred from the claim text.