Process for producing sulfur
AssigneeMetallgesellschaft Aktiengesellschaft
InventorsHeinz Hiller, Herbert Fischer
Life of this patent
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Abstract
The gases discharged from the sulfur condenser of a Claus process reactor are contacted with an active adsorbent to remove further sulfur and the resulting exhaust gas is afterburned. A desorption gas is passed in closed cycle through the laden adsorbent and is heated, in this cycle, in heat exchange with the hot gases emerging from the afterburner. The sulfur is condensed from the desorption gas with the same cooling system used for the Claus process condensation and water vapor produced by the cooling system is condensed and by gravity is returned to the condensation stage.
Claims7
A process for producing sulfur from an acid gas containing hydrogen sulfide and other sulfur compounds, said process comprising
- a. combusting said acid gas partially to produce a process gas stream containing hydrogen sulfide sulfur and sulfur dioxide;
- b. catalytically reacting the hydrogen sulfide, with sulfur dioxide in said process gas stream in a Claus process reactor and condensing sulfur from the catalytically reacted stream with a cooling system to produce a further gas stream containing residual sulfurous components;
- c. passing said further gas stream at a lower temperature than that of the catalytic reaction of step (b) over an active adsorbent to load said adsorbent with sulfur and produce another gas stream;
- d. afterburning the gas stream produced in step (c) which still contains rasidual sulfur and residual H.sub.2 S with oxygen to produce a hot exhaust gas stream substantially free from hydrogen sulfide and sulfur and consisting mainly of sulfur dioxide;
- e. desorbing the laden adsorbent from step (c)by
- e.sub.1. circulating a desorption gas in closed cycle through said laden adsorbent;
- e.sub.2. heating said desorption gas before it contacts said laden adsorbent along said closed cycle by passing it in heat exchange with said hot exhaust gas from step (d);
- and
- e.sub.3. condensing sulfur from said desorption gas after it has contacted said laden adsorbent along said cycle with said cooling system from step (b),
- e.sub.4. said cooling system containing water;
- f. generating water vapor thereby by said cooling, and
- g. condensing said generated water vapor and recycling same by gravity to step (e.sub.3) to condense the sulfur.
Dependencies are inferred from the claim text.