Epoxide thermal stabilization additive for polypyrrolidone
AssigneeChevron Research Company
InventorPhillip H. Parker
Life of this patent
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Abstract
Alkyl epoxides are thermal stabilization additives for normally solid polypyrrolidone at melt temperatures.
Claims16
A composition of matter comprising a major amount of normally solid poly-2-pyrrolidone and a thermal stabilizing amount, effective to reduce the thermal degradation of said poly-2-pyrrolidone to its monomer, of an alkyl epoxide, containing less than about 60 carbon atoms, of the formula ##STR2## wherein R is hydrogen, alkyl or epoxyalkyl and R' is alkyl, polyalkylene oxide, epoxyalkyl, epoxypolyalkyl oxide, alkylester, epoxyalkylester, hydroxyalkyl or hydroxyalkylester.
A composition of matter comprising a major amount of a normally solid poly-2-pyrrolidone and a minor amount of an epoxyalkane, containing less than about 60 carbon atoms, effective to reduce the thermal degradation of said poly-2-pyrrolidone to it monomer.
A composition of matter comprising a major amount of normally solid poly-2-pyrrolidone and a minor amount effective to reduce the thermal degradation of said poly-2-pyrrolidone to its monomer of an epoxidized ester, of a fatty acid, containing less than about 60 carbon atoms.
A method of melt extruding normally solid polypyrrolidone comprising admixing a thermal-stabilizing amount effective to reduce the thermal degradation of said poly-2-pyrrolidone to its monomer of an alkyl epoxide, containing less than about 60 carbon atoms, of the formula ##STR3## wherein R is hydrogen, alkyl or epoxyalkyl and R' is alkyl, polyalkylene oxide, epoxyalkyl, epoxypolyalkyl oxide, alkyl ester, epoxyalkyl ester, hydroxy alkyl or hydroxy alkyl ester, with said polypyrrolidone to form a mixture, and extruding said mixture at a melt temperature in the range of about 260.degree.-280.degree. C.
Dependencies are inferred from the claim text.