Process for preparation of sodium percarbonate or sodium perborate of high specific volume

A process for preparing sodium percarbonate having a specific volume of from 5 to 10 cc/g, which consists essentially of the steps of:

• mixing (1) sodium carbonate or an aqueous solution of sodium carbonate, with (2) an aqueous solution of hydrogen peroxide, wherein at least one of said solutions has dissolved therein a water-soluble anionic organic surfactant selected from the group consisting of the sodium, potassium, ammonium and alkylol ammonium salts of higher fatty acids or resin salts containing about 8 to 20 carbon atoms;
• alkyl benzene sulfonates, alkyl phenol sulfonates and alkyl naphthalene sulfonates in which the alkyl group has from 8 to 18 carbon atoms;
• olefin sulfonates, hydroxyalkane sulfonates and mixtures thereof obtained from olefins having 8 to 25 carbon atoms;
• alkyl sulfonates and disulfonates in which the alkyl group has from 10 to 20 carbon atoms;
• salts of higher fatty acids having 8 to 20 carbon atoms esterified with isethionic acid;
• sulfates of higher alcohols having 8 to 18 carbon atoms;
• sulfates of mono- or di-glycerides of higher (C.sub.10 - C.sub.18) fatty acids;
• polyoxyethylene alkyl ether sulfates containing 1 to 6 moles of ethylene oxide and in which the alkyl contains from 8 to 18 carbon atoms;
• polyoxyethylene alkylphenol ether sulfates containing 1 to 10 moles of ethylene oxide and in which the alkyl contains 8 to 12 carbon atoms;
• and sulfates of alkanolamides of higher fatty acids having 12 to 18 carbon atoms, wherein the concentration of said surfactant in the mixture of (1) and (2) is higher than the critical concentration for micelle formation of said surfactant and is less than about 5 percent by weight, based on the weight of said mixture, whereby to precipitate crystals of sodium percarbonate;
• and recovering said crystals of sodium percarbonate from said mixture.