Method of consolidating porous formations using vinyl polymer sealer with divinylbenzene crosslinker
AssigneeHalliburton Company
InventorHomer Charles McLaughlin
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Abstract
An improved method and composition for consolidating a porous and permeable subterranean particulated formation into a high strength water resistant mass is provided by a particular combination of vinyl monomers, catalyst system and optional features such as solvent, particulate filler, chelates and binders.
Claims17
A method of consolidating a porous permeable formation using a consolidating composition which is not sensitive to pH, carbonates or water comprising contacting said formation with a polymerizable organic liquid mixture of (1) at least one vinyl type monomer having about 3-12 carbon atoms and containing at least one group from phenyl, carboxyl or nitrile and (2) at least one divinyl type monomer having about 3-12 carbon atoms, wherein each of said monomers is soluble in a low viscosity liquid aromatic hydrocarbon solvent;
- wherein said polymerizable mixture contains a polymerization promoter and a polymerization initiator comprising an organic peroxide, an azo compound or a combination thereof;
- and maintaining said polymerizable organic liquid mixture in contact with said formation until the monomers in said liquid mixture polymerize with the polymer chain and crosslink, having substantially all hydrocarbon linkages forming a crosslinked consolidated mass having a compressive strength after 24 hours of at least 120 psi.
A method of consolidating a porous permeable formation of claim 16 wherein the polymerizable organic liquid is applied to said formation to seal said formation, reducing the flow of fluids through said formation.
Dependencies are inferred from the claim text.