Polyester lubricant additives, their preparation and compositions containing them
AssigneeEdwin Cooper, Inc.
InventorsJohn Scotchford Elliott, Bryan Terence Davis, Stephen Norman
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Abstract
Polyesters suitable for use as lubricant additives are prepared by reacting a di-carboxylic acid or anhydride having a branched chain alkyl or alkenyl substituent containing at least 30 carbon atoms with a compound having the formula: ##STR1## wherein R and R.sup.1 are specified substituents which between them possess from 2 to 6 free hydroxyl groups. Lubricating compositions containing these polyester additives are also described.
Claims13
A polyester suitable for use as a lubricant additive which is the product of the reaction at elevated temperature from reflux up to about 210.degree. C. with removal of water of a polyolefin substituted succinic acid or anhydride wherein said polyolefin substituent has a molecular weight of about 700-3,000 with a substituted carboxypyrrolidone of the following formula A ##STR14## in which a. R is selected from the group consisting of a hydrogen atom, an alkyl containing up to 8 carbon atoms, a phenyl group, a benzyl group, a hydroxyalkyl group containing 1-3 hydroxy radicals, a polyoxyalkylenealkyl group containing up to an average of about 2 oxyalkylene groups, a hydroxyalkylaminoalkyl group, a carboxypyrrolidone substituted C.sub.2-6 alkyl group, and an imidazoline substituted C.sub.1-4 alkyl group,
- b. each R.sup.1 is independently selected from a group consisting of ##STR15## c. R.sup.2 is alkylene containing 2-6 carbon atoms d. R.sup.6 is selected from the group consisting of alkyl groups containing up to 8 carbon atoms, polyoxylalkyene alkyl groups containing up to an average of about 2 oxyalkylene groups, hydroxyalkyl groups containing 1-3 hydroxy radicals, imidazoline substituted C.sub.1-4 alkyl groups, and groups having the formula ##STR16## in which the groups R and R.sup.2 independently are as herein defined, e. R.sup.7 is selected from the group consisting of alkyl groups containing up to 8 carbon atoms, hydroxyalkyl groups containing 1-3 hydroxy radicals, dialkylaminoalkyl groups, hydroxyalkylaminoalkyl groups, imidazoline substituted C.sub.1-4 alkyl groups, groups having the formula ##STR17## and groups having the formula ##STR18## in which the groups R and R.sup.2 independently are as herein defined, f. R.sup.8 is selected from the group consisting of hydrogen, alkyl groups containing up to 8 carbon atoms, hydroxyalkyl groups containing up to 3 hydroxy groups, dialkyl aminoalkyl groups, imidazoline substituted C.sub.1-4 alkyl groups, hydroxyalkylaminoalkyl groups and groups having the formula ##STR19## in which the groups R and R.sup.2 independently are as herein defined, and g. provided that there are a total of from 2-6 free hydroxy groups on groups R and/or R.sup.1.
A polyester lubricant additive made by the process comprising reacting at elevated temperature of about 80.degree.-180.degree. C, a hydroxyamine compound selected from the group consisting of monohydroxyalkyl amines and dihydroxyalkyl aminoalkyl amines with itaconic acid or alkyl esters thereof to form an intermediate carboxypyrrolidone compound and reacting said intermediate at elevated temperature from reflux up to about 210.degree. C. with removal of water with a polyolefin substituted succinic acid or anhydride, said polyolefin substituent having a molecular weight of about 700-3,000.
Dependencies are inferred from the claim text.