Method of removing dissolved organo-lead compounds from water
AssigneePPG Industries, Inc.
InventorJack M. Otto
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Abstract
Disclosed is a method of removing ionizable organo-lead compounds from aqueous liquid compositions. The ionizable organo-lead compounds contemplated herein are those with cations having the formula; (PbR.sub.4-x).sup.+x where the R's are alkyl and aryl groups and x is an integer from 0 to 3. The liquid composition typically contains from about 1 to about 20 parts per million by weight of the organo-lead compound. According to the method of this invention, the liquid composition is fed to a bed of activated carbon and passed through the bed. A liquid composition is recovered, reduced in ionizable organo-lead content, for example, an organo-lead content less than about one part per million.
Claims8
A method of removing water soluble organo-lead salts chosen from the group having cations consisting of (PbR.sub.3).sup.+1, (PbR.sub.2).sup.+2, (PbR).sup.+3, and mixtures thereof, where R is chosen from the group consisting of aryl groups and alkyl groups having from 1 to 8 carbon atoms from an aqueous liquid composition containing more than 1 part per million of said salts comprising:
- passing the aqueous composition through a packed bed of activated carbon;
- adsorbing the organo-lead salts onto the activated carbon;
- and
- recovering the aqueous liquid composition, reduced in organo-lead content to less than 1 part per million of the organo-lead salts, from the packed bed.
A method of removing dissolved water soluble organo-lead compounds chosen from the group consisting of triethyl lead chloride, diethyl lead dichloride, ethyl lead dichloride, trimethyl lead chloride, dimethyl lead dichloride, methyl lead dichloride, and mixtures thereof, from an aqueous liquid composition substantially free of inorganic lead compounds and tetra alkyl lead compounds and containing from about 1 to about 20 parts per million of the water soluble organo-lead compounds, which method comprises:
- passing the aqueous liquid composition through a packed bed of activated carbon;
- adsorbing the organo-lead compounds onto the activated carbon;
- and
- recovering the aqueous liquid composition, reduced in organo-lead content to less than 1 part per million, from the packed bed.
A method of treating a lead-containing aqueous composition containing inorganic lead compounds, tetra alkyl lead, and more than 1 part per million of dissolved ionizable organo-lead compounds, which method comprises:
- adjusting the pH of the liquid composition to between pH = 9.0 and pH = 10.0 whereby to precipitate the inorganic lead compounds;
- physically separating inorganic lead compounds and tetra alkyl lead compounds from the liquid composition;
- passing the liquid composition containing more than 1 part per million of dissolved ionizable organo-lead compounds through a bed of activated carbon whereby to adsorb the organo-lead compounds onto the activated carbon, thereby removing dissolved, ionizable organo-lead compounds from the liquid composition;
- and
- recovering a liquid composition containing less than 1 part per million of ionizable organo-lead compounds from the activated carbon bed.
Dependencies are inferred from the claim text.