Cyclopentene derivatives
AssigneeBASF SE
InventorsWerner Hoffmann, Karl VON Fraunberg
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Abstract
Cyclopentene derivatives (I) ##STR1## where R.sup.1 is isopropyl or isopropenyl, R.sup.2 is alkyl of 1 to 3 carbon atoms, X is --CHO, a dialkyl acetal or 1,2- or 1,3-alkylene acetal thereof where the acetal radical is of 2 to 6 carbon atoms, --CH.sub.2 OH or --CH.sub.2 OCOR.sup.3 where R.sup.3 is hydrogen or alkyl or alkenyl of up to 3 carbon atoms. The manufacture of I from the corresponding halomethyl cyclopentenes and aldehydes R.sup.2 --CH(CH.sub.3)--CHO in the presence of a base and a quaternary ammonium salt, followed if desired by acetalization or conversion of the --CHO group to the --CH.sub.2 OH or --CH.sub.2 O--CO--R.sup.3 groups. The compounds are useful as fragrance materials.
Claims1
A process for the manufacture of a cyclopentene derivative of the formula I ##STR9## where R.sup.1 is isopropyl or isopropenyl, R.sup.2 is alkyl of 1 to 3 carbon atoms, X is CHO which comprises:
- reacting a compound of the formula II ##STR10## where Y is halogen with an aldehyde of the formula III ##STR11## in the presence of an aqueous solution of a strong base and in the presence of a catalytic amount of a quaternary ammonium salt.
Dependencies are inferred from the claim text.