Opacified latex paint containing plastic polymer particles
AssigneeSCM Corporation
InventorAlex Ramig
Life of this patent
Estimating the term…
Abstract
An opacified latex dispersion paint composition comprises film-forming latex binder having a major weight proportion of polymer particles not smaller than about 1,000 A, non-film-forming plastic polymer particles having a weighted average particle size diameter between about 1,000 A and 10,000 A, and opacifying pigment. The latex paint is compounded at a pigment-volume-content (PVC) greater than the critical-PVC as measured by opacity and provides improved opacified paint film having excellent film integrity properties.
Claims10
An aqueous latex dispersion paint composition which coalesces at an ambient coalescing temperature into a hardened paint film, said latex paint having about 30% to 70% by weight total solids and comprising on a dry solids volume basis:
- 25% to 70% of a film-forming latex binder having a major weight portion of polymer particles between about 1,000 A and 10,000 A and having a glass transition temperature at least about 5.degree. C. below said coalescing temperature whereby said binder particles will coalesce into a binding matrix, said latex binder being a polymer or a copolymer derived from ethylenically unsaturated monomers;
- 10% to 60% of solid, non-cellular, non-film-forming polymer particles having a weighted average diameter between about 1,000 A and 10,000 A and having a glass transition temperature at least about 30.degree. C. above the glass transition temperature of said binder, said non-film-forming particles being polymerized ethylenically unsaturated monomers having carbon-to-carbon unsaturation;
- 5% to 25% opacifying pigment having a refractive index of at least about 1.8 and being in a volumetric proportion less than the volumetric proportion of said non-film-forming polymer particles;
- 0% to 60% of non-opacifying pigment;
- and
- said latex paint having a pigment-volume-content (PVC) between about 30% to 75% wherein the PVC is greater than the critical-PVC (opacity) as measured by the lower break in the opacity curve.
An aqueous latex dispersion paint composition which coalesces at an ambient coalescing temperature into a hardened paint film, said latex paint having about 30% to 70% by weight total solids and comprising on a dry solids volume basis:
- 25% to 70% of a film-forming latex binder having a major weight portion of polymer particles not smaller than 1,000 A and having a glass transition temperature at least about 5.degree. C. below said coalescing temperature whereby said binder particles will coalesce into a binding matrix, said latex binders being polymers and copolymers derived from ethylenically unsaturated monomers;
- 5% to 70% of solid, non-cellular, non-film-forming polymer particles having a weighted average diameter between about 1,000 A and 10,000 A and having a glass transition temperature at least about 25.degree. C. above said coalescing temperature and at least about 30.degree. C. above the glass transition temperature of said binder, said non-film-forming particles being polymerized organic liquids having carbon-to-carbon unsaturation;
- 5% to 30% opacifying pigment having a refractive index of at least about 1.8 and being a volumetric proportion less than the volumetric proportion of said non-film-forming polymer particles;
- 0% to 60% of extender and filler pigments other than said opacifying pigment;
- and
- said latex paint having a pigment-volume-content (PVC) greater than the critical-PVC (opacity) as measured by the lower break in the opacity curve, and said pigment-volume-content (PVC) being less than the critical surface porosity-PVC (enamel holdout) as measured by the upper break in the enamel holdout curve.
An aqueous latex dispersion paint composition which coalesces at an ambient coalescent temperature into a hardened paint film, said latex paint having about 30% to 70% by weight total solids and comprising on a dry solids volume basis:
- 25% to 70% of a film-forming latex binder having a major weight portion of polymer particles between about 1,000 A and 10,000 A and having a glass transition temperature at least about 5.degree. C. below said coalescing temperature whereby said binder particles will coalesce into a binding matrix, said latex binder being a polymer of a copolymer derived from ethylenically unsaturated monomers;
- 5% to 60% of solid, non-cellular, non-film-forming polymer particles having a weighted average diameter between about 1,000 A and 10,000 A and having a glass transition temperature at least about 30.degree. C. above the glass transition temperature of said binder, said non-film-forming particles being polymerized ethylenically unsaturated monomers having carbon-to-carbon unsaturation;
- 5% to 25% opacifying pigment having a refractive index of at least about 1.8;
- 0% to 60% of non-opacifying pigment;
- and
- said latex paint having a pigment-volume-content (PVC) greater than the critical -PVC (opacity) as measured by the lower break in the opacity curve, and said pigment-volume-content (PVC) being less than the critical surface porosity-PVC (enamel holdout) as measured by the upper break in the enamel holdout curve.
Dependencies are inferred from the claim text.