Hydrogen-producing hydrocarbon conversion with gravity-flowing catalyst particles
OwnerArthur R. Greenwoodinventor
Life of this patent
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Abstract
A multiple-stage catalytic conversion system in which a hydrocarbonaceous charge stock is reacted in a plurality of stacked catalytic reaction zones through which catalyst particles flow downwardly via gravity-flow. The charge stock, in the absence of added, or recycle hydrogen, is reacted first in the lowermost reaction zone, from which deactivated catalyst particles are withdrawn from the system. Resulting reaction zone effluent is further reacted in the uppermost reaction zone, through which fresh, or regenerated catalyst particles are introduced into the system, and serially in one or more subsequent, lower reaction zones. Product effluent from the reaction zone immediately above the lowermost zone is separated to recover the desired normally liquid product.
Claims10
A process for the catalytic reforming of a naphtha charge stock with a catalyst comprising a Group VIII noble metal on an alumina support to produce a gasoline fraction of higher octane number in a multiple-stage system in which (1) catalyst particles flow downwardly, via gravity, through each reaction zone in said system, (2) catalyst particles are transferred in series from reaction zone to reaction zone in said system, (3) deactivated catalyst particles are withdrawn from said system through the lower end of the last reaction zone, and, (4) fresh, or regenerated catalyst particles are introduced into the upper end of the first reaction zone, which comprises the sequential steps of:
- a. reacting said charge stock, in the absence of added or recycled hydrogen, in said last reaction zone, from which deactivated catalyst particles are withdrawn from said system, at catalytic reforming conditions;
- b. further reacting the effluent from said last reaction zone in said first reaction zone, through which fresh or regenerated catalyst particles are introduced into said system, at catalytic reforming conditions;
- c. further reacting the effluent from said first reaction zone in at least one intermediate reaction zone, at catalytic reforming conditions;
- and,
- d. recovering a normally liquid, catalytically-reformed product from the effluent withdrawn from said intermediate zone.
A multiple-stage catalytic reforming of a naphtha charge stock with a catalyst comprising a Group VIII noble metal on an alumina carrier to produce a gasoline fraction of higher octane number than said naphtha which comprises the steps of:
- a. introducing fresh, or regenerated catalyst particles into the upper end of a first reaction zone, through which said particles are movable via gravity-flow, and transferring catalyst particles from the lower end of said first zone into the upper end of a second reaction zone, through which said catalyst particles are movable via gravity-flow;
- b. transferring catalyst particles from the lower end of said second zone and introducing them into the upper end of a third reaction zone, through which catalyst particles are movable via gravity-flow;
- c. transferring catalyst particles from the lower end of said third zone and introducing them into the upper end of a fourth reaction zone, through which catalyst particles are movable via gravity-flow, and withdrawing deactivated catalyst particles from the lower end of said fourth zone;
- d. reacting a hydrocarbon charge stock, in the absence of added or recycled hydrogen, in said fourth reaction zone at catalytic reforming conditions;
- e. further reacting the resulting fourth zone effluent in said first reaction zone at catalytic reforming conditions;
- f. further reacting the resulting first zone effluent in said second reaction zone at catalytic reforming conditions;
- g. further reacting the resulting second zone effluent in said third reaction zone at catalytic reforming conditions;
- and,
- h. recovering a normally liquid, catalytically-reformed product from the resulting third reaction zone effluent.
Dependencies are inferred from the claim text.