Method of electrochemically forming a lithium silicon iron alloy electrode

A method for electrochemically forming a composite negative lithium electrode structure for an electrical energy storage device from the uncharged state, wherein the formed negative electrode structure comprises a supporting current-collecting matrix in intimate contact with an alloy of lithium, silicon, and iron having the empirical formula Li.sub.x SiFe.sub.y, where x has a value from 1 to 5 and y has a value from 0.125 to 1, which includes the steps of:

• providing a supporting current-collecting matrix in intimate contact with an alloy of iron and silicon, the iron being present in an amount from about 11 to 50 atom percent and the silicon being present in an amount from about 89 to 50 atom percent;
• immersing the current-collecting matrix containing the iron-silicon alloy in a lithium-containing molten salt electrolyte in a cell in opposing relation to a positive electrode structure, and
• electrochemically charging the iron-silicon electrode structure at a selected voltage or current for a time sufficient to form said lithium-silicon-iron alloy negative electrode structure.