Selective production of para-xylene
AssigneeMobil Oil Corporation
InventorWarren W. Kaeding
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Abstract
A catalytic process is provided for the selective production of para-xylene by contacting, under conversion conditions, a charge stock containing, as a major reactant, at least one hydrocarbon selected from the group consisting of toluene, a C.sub.3 -C.sub.10 olefin and mixtures of the foregoing with a catalyst comprising a crystalline aluminosilicate zeolite having a silica to alumina ratio of at least about 12, a constraint index, as hereinafter defined, within the approximate range of 1 to 12 and having combined therewith boron in an amount of at least about 0.2 percent by weight.
Claims13
A process for the selective production of para-xylene which comprises contacting toluene, under methylation conditions, with a methylating agent in the presence of a catalyst consisting essentially of a crystalline aluminosilicate zeolite having a silica to alumina ratio of at least about 12 and a constraint index within the approximate range of 1 to 12, said zeolite having combined therewith boron in an amount of at least about 0.2 percent by weight as a result of reaction of said zeolite with a boron-containing compound selected from the group consisting of boric acid, trimethylborate, boron hydride, boron oxide, boron sulfide, butylboron dimethoxide, butylboronic acid, dimethylboric anhydride, hexamethylborazine, phenylboric acid, triethylborane, tetramethylammonium borohydride, triphenyl boron and allylborate;
- cooling the resulting product and separating para-xylene therefrom.
Dependencies are inferred from the claim text.