Non-cyanide acidic silver electroplating bath and additive therefore
AssigneeOxy Metal Industries Corporation
InventorsElizabeth P. Leahy, George A. Karustis
Life of this patent
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Abstract
A non-cyanide acidic silver electroplating bath contains a soluble silver salt, a thiosulfate, a bisulfite buffer and a sulfate.
Claims4
An aqueous non-cyanide acidic silver electoplating bath, which comprises a water soluble silver salt in a concentration of about 5 to 50 grams of silver per liter of solution, sodium thiosulfate present in an amount of about two moles of thiosulfate for each mole of silver in said silver salt, a bisulphite buffer in the form of sodium bisulphite present in an amount of about 4 grams per liter to saturation, and a sulfate in the form of an alkaline metal sulfate present in an amount of about 4 grams per liter to saturation, said solution having a pH of about 3.5 to 7.0, said solution further including a brightener system which comprises at least one anionic sulfonic acid derivative surfactant, at least one amphoteric nitrogen containing carboxylic or sulfonic derivative surfactant, at least one cationic or non-ionic surfactant, at least one solution stable soluble aldehyde, and at least one C=S containing compound or tautomer thereof.
A brightener system especially adapted for use in aqueous non-cyanide acid silver electroplating solutions which comprises, in aqueous solution, at least one anionic sulfonic acid derivative surfactant, at least one amphoteric nitrogen containing carboxylic or sulfonic derivative surfactant, at least one cationic or non-ionic surfactant, at least one electrolysis stable soluble aldehyde, and at least one C=S containing compound or tautomer thereof.
Dependencies are inferred from the claim text.