Heat resistant and flame resistant papers
AssigneeKanebo, Ltd.
InventorsKoichiro Ohtomo, Tsuyoshi Nakamo
Life of this patent
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Abstract
Heat resistant and flame resistant papers composed of at least 60% by weight of phenolic fibers having a hardened degree of 3-30% by weight, which are obtained by melt spinning a phenolic resin and cross-linking the resulting filaments with an aldehyde.
Claims12
A hot pressed, heat resistant and flame resistant paper containing from 60 to 99.5 percent by weight of infusible, non-flammable phenolic fibers having fiber lengths in the range of 0.3 to 100 mm and from 0.5 to 30 percent by weight of a hardened epoxy resin as a binder, said phenolic fibers having been prepared by either (1) immersing novolak fibers in a first aqueous solution containing 0.1 to 25 percent by weight of a strong acid and 0.5 to 35 percent by weight of an aldehyde at room temperature for zero to 2 hours, raising the temperature of the first solution to from 50.degree. to 105.degree. C in from 0.50 to 10 hours and then maintaining the first solution at from 50.degree. to 105.degree. C for from zero to 2 hours to harden the outer layer of the fibers, then immersing the fibers in a second aqueous solution containing 0.2 to 15 percent by weight of ammonia or amines and one to 35 percent by weight of an aldehyde at room temperature, then raising the temperature of said second solution to 70.degree. to 95.degree. C in from 0.5 to 1 hour and then maintaining the solution at 70.degree. to 95.degree. C for 0.5 to 10 hours until the weight of the starting novolak fibers are increased from 3 to 30 percent by weight as a result of cross-linking, or (2) immersing novolak fibers in said first solution at room temperature for zero to 2 hours, raising the temperature of said first solution to 50.degree. to 105.degree. C in from 0.05 to 10 hours and then maintaining said first solution at 50.degree. to 105.degree. C for zero to 20 hours until the weight of the starting novolak fibers has increased from 3 to 30 percent by weight as a result of cross-linking,
- said epoxy resin being an addition product of a bisphenol or a halogenated bisphenol with epichlorohydrin.
A hot-pressed, heat resistant and flame resistant paper containing from 60 to 99.5 percent by weight of infusible, non-flammable phenolic fibers having fiber lengths in the range of 0.03 to 100 mm and from 0.5 to 30 percent by weight of a hardened epoxy resin as a binder, said phenolic fibers having been prepared by immersing novolak fibers in a first aqueous solution containing 0.1 to 25 percent by weight of a strong acid and 0.5 to 35 percent by weight of an aldehyde at room temperature for zero to 2 hours, raising the temperature of the first solution to from 50.degree. to 105.degree. C in from 0.05 to 10 hours and then maintaining the first solution at from 50.degree. to 105.degree. C for from zero to 2 hours to harden the outer layer of the fibers, then immersing the fibers in a second aqueous solution containing 0.1 to 25 percent by weight of an acidic catalyst or a basic catalyst, one to 30 percent by weight of an aldehyde, 0.5 to 15 percent by weight of a substance selected from the group consisting of urea, thiourea, methylol derivatives of urea and thiourea, ethyleneurea, ethylenethiourea and methylol derivatives of ethylene urea and ethylenethiourea, and one to 50 percent by weight of an alcohol, a ketone or an ether, at room temperature, then raising the temperature of said second solution to 50.degree. to 95.degree. C in from 0.5 to 2 hours and then maintaining the second solution at 50.degree. to 95.degree. C for 0.5 to 25 hours until the weight of the starting novolak fibers has increased from 3 to 30 percent by weight as a result of cross-linking,
- said epoxy resin being an addition product of a bisphenol or a halogenated bisphenol with epichlorohydrin.
Dependencies are inferred from the claim text.