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AssigneeExxon Research & Engineering Co.
InventorsRobert B. Long, Fred A. Caruso, Richard J. DeFeo, David G. Walker
Estimating the term…
Bimetallic salts, having the generic formula MM'X.sub.n wherein M is a Group IB metal, M' is a Group IIIA metal, X is a halide and n is equal to the sum of the valences of M and M', are prepared by reacting the halogen salts of the individual metals, M and M', in a suitable solvent. The bimetallic salt formed thereby is a discrete monomeric species and can be utilized in the separation and recovery of various ligands, by preferential complexation. Complexation can be conducted with the bimetallic salt in the solid state, in solution, or as a slurry, and with the complexible ligand in the gaseous or liquid state. The ligand is recovered by decomplexation of the bimetallic salt-ligand complex or by displacement of the complexed ligand with another ligand.
A complex bimetallic salt having the generic formula CuAlX.sub.4 L.sub.m wherein X is selected from the group consisting of chlorine, bromine and fluorine atoms, L is a complexible ligand selected from the group consisting of a C.sub.2 -C.sub.6 acetylene, a C.sub.4 -C.sub.10 conjugated diolefin, a C.sub.6 -C.sub.16 polyolefin, a C.sub.5 -C.sub.10 cyclic olefin and a C.sub.3 -C.sub.6 diolefin and m is equal to the complexing stoichiometry of L and is an integer ranging from 1 to 4.
A complex bimetallic salt having the generic formula CuAlCl.sub.4 L.sub.m wherein L is a C.sub.2 -C.sub.6 acetylene and m is an integer ranging from 1 to 4.
A compound that has the structural formula RC.tbd.CH:Cu(AlCl.sub.4)
Dependencies are inferred from the claim text.